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Safer, Higher-Capacity Batteries

Silver-zinc battery chemistry could replace lithium ion in laptops and other electronics--if such batteries can be made cheaply enough.

By Kevin Bullis

Wednesday, October 11, 2006

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An alternative to lithium-ion batteries--silver-zinc batteries--could add several hours to the time that laptops can run between charges, while at the same time avoiding the safety issues that have resulted in the recent massive recalls of laptop batteries made by Sony, according to Zinc Matrix Power in Camarillo, CA.

Zinc Matrix Power of Camarillo, CA, is working on a laptop battery pack that it says could double capacity--and also not catch fire. (Credit: Zinc Matrix Power)

The company, which received an innovation award from Intel last month for its new battery, has now demonstrated the silver-zinc technology in a laptop. Zinc Matrix plans to begin distributing test batteries to manufacturers early next year, focusing on applications in laptops and cell phones.

In part, the gains in laptop runtimes would come because the silver-zinc batteries can store about 25 percent more energy in the same space, a result of both the chemistry and a more space-efficient flat shape, compared with cylindrical lithium-ion cells inside laptop battery packs, says Ross Dueber, president and CEO of Zinc Matrix Power. What's more, because silver-zinc batteries use a safer chemistry than most lithium-ion batteries, manufacturers could use larger batteries packs in laptops.

Silver-zinc rechargeable batteries are not new--for example, they've been used by the Navy in submarines for years. But they've been plagued by high costs due to the use of silver, and by a short lifespan because they can be charged and discharged for only a relatively few cycles, and so have to be replaced more frequently than other types of batteries.

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Dueber says the company plans to keep down the costs with a recycling program that will allow it to reuse the silver and zinc. And it has extended the charging cycle-life to hundreds of cycles--similar to many lithium-ion batteries. One of the reasons for the previously low cycle-life is that, as the batteries charge and recharge, zinc in the cell undergoes physical changes that lead to decreasing cell capacities. The company addressed this problem by embedding zinc granules within a conductive polymer.

The safety of the batteries in part results from the use of a nonflammable electrolyte. "It is an inherently safe technology in comparison to lithium ion," Dueber says. "The fundamental difference is we do not use a highly flammable electrolyte, like lithium ion does. If you have an internal short circuit, which has recently plagued lithium ion, it does not have the possibility of bursting into flames and exploding."

Comments

  • every day - a new battery
    All this recent intense development on new rechargeable battery systems bodes well for the electricity-centric future. Odds are that at least some of these guys will make it to market. But I'd like to know where this leaves fuel cells & methanol/ethanol/hydrogen/reformers.
    Rate this comment: 12345

    SVE
    10/11/2006
    Posts:48
    Avg Rating:
    3/5
    • Re: every day - a new battery
      Indeed, new chemistries are being used every day. But it is a lot like both the early days of radio and home computers. New companies, new products, most being left in the dust. It is going too fast for much financial security for investors, which is scary.
      Recycling sounds good, but really, unless there is a financial incentive that makes people want to take the time and trouble to bring them in, they will be dumped. This could be good for silver mining, and there is no shortage of silver.
      For fuel cells,,, they actually generate energy, whereas the batteries just store them. It could be a matter of niches, where the particular product works best.
      Rate this comment: 12345

      kitk
      10/11/2006
      Posts:66
      Avg Rating:
      3/5
      • Re: every day - a new battery
        Um, fuel cells don't generate electricity.  They act like the internal workings of battery, with a chemical reaction creating electricity.  Fuel cells even fail here in that they can't even store the "fuel" like a battery, they need heavy external tanks for the compressed hydrogen.  And while there is no shortage of silver, it isn't that common and is only found in very low concentrations.  For the most part, silver is now a byproduct of copper mining.  Seems like a poor solution; I would stick with the Li-ion chemistries.  Especially since companies like Altair Nano and A123 seem to have already solved the safety issues.
        Rate this comment: 12345

        mjtimber
        10/13/2006
        Posts:6
        Avg Rating:
        3/5
  • Is Safe Using Li-ion  Battery ?
    from http://www.Camcorder-battery-shop.com 2006-10-28

    Some customer ask me the question"Is Safe Using Li-ion Camcorder Battery", as there are too many event of "battery recall" at present.the following is my answer.

    There is the rare possibility that any battery can explode. Some battery designs are more prone to this than others. Being a name brand battery isn't always a good indicator that a battery isn't one of those that might possibly explode. Sometimes even name brand stuff does this.

    These things are very rare but it does happen. This is the one thing you might be concerned about when it comes to batteries. BTW camera companies buy their batteries from a company that makes batteries for the most part. The only thing you can do is to check for reports of explosions on the web. In the past there was no good way of finding out these things without making a trip to the periodicals section of a good library.

    I buy lots of aftermarket batteries. I generally try to check about a retailer since it's often hard to know exactly what batteries are being sold. If you find a dealer that is known to sell lots of batteries that don't have problems then you shouldn't have any problems.

    Like I said, I have all sorts of batteries from a number of manufacturers and I've never had any problems with explosions. I have had batteries that really weren't all that good. The worst ones I have were actually Panasonic but I strongly suspect I used a charger that was too powerful for them.

    Li-ion batteries do not explode, at least I have never been able to find a reliable report of the battery exploding however they have been reported to get very hot, hot enough to reach 6,000 degrees which could in some cases being more dangerous than exploding.

    The reference given seems to be a bit outdated. It states "Similarly, Li-ion batteries for defense applications are being produced that far exceed the energy density of the commercial equivalent. Unfortunately, these super-high capacity Li-ion batteries are deemed unsafe in the hands of the public. Neither would the general public be able to afford to buy them" There are actually several Li-ion battery chemistries used but even the consumer Li-ion batteries can be dangerous if you try to cut them open or puncture them.

    Most camcorders today use the Li-ion batteries, as well as cellphones and a lot of laptops.
    Rate this comment: 12345

    tancecom
    11/13/2006
    Posts:2
  • better than Zinc matrix
    Surely we don't think the zinc matrix is the cure all the major battery and laptop companies, dell, sony, lonovo, LG, toshiba.... are all awaiting the release 1stQ 07 of disruptive technology in the small battery field.   they know, but it is not yet public knowledge that the new microvascular battery from SigFx will eliminate the heat problem and increase battery life 2-300% a phenomenal increase.  this 8 year project has been below the radar but will be publically announced in the next 4-8 weeks.  no efforts to get the word out, but now is the time,   ask around to the larger players battery and computer, and you will be able to get some vague limited info.   check out the tech presentation at http://www.sigfx.com/index.html
    Rate this comment: 12345

    rhogan1
    11/21/2006
    Posts:3
    Avg Rating:
    1/5

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