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Safer, Longer-Lasting Batteries for Cars

A startup company has a printing method for solid-state batteries.

By Katherine Bourzac

Tuesday, July 20, 2010

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An Orlando startup has developed new manufacturing techniques that could improve the stability and lifetime of batteries used in electric vehicles. Planar Energy, a spin-off of the National Renewable Energy Laboratories (NREL), is working on scaling up solid-state lithium-ion batteries.

Solid power: Planar Energy CEO Scott Faris holds a solid-state battery cathode printed using new manufacturing techniques.
Credit: Planar Energy

Conventional batteries, which typically use a liquid electrolyte, can suffer from undesirable chemical reactions that damage the battery's cathode. Replacing the liquid electrolyte with a solid ion conductor can improve battery stability and lifetime, and also allow a battery to be smaller because additional components aren't needed to maintain stability. Solid electrolytes are also compatible with a wider range of battery chemistries that could potentially offer higher power or storage density.

But solid-state batteries are expensive to make and have been difficult to scale up to the size needed for laptops or vehicles. Like other solid-state devices, solid-state batteries are normally made using complex, costly, vacuum-based deposition methods. The vacuum deposition limits the thickness of solid-state batteries, which, in turn, limits their energy storage capacity. So these thin-film batteries have been limited to use in small devices.

Efforts to use printing processes to make thicker solid-state batteries have been stymied by the lack of a printable solid electrolyte material (printed electrodes must usually be combined with a liquid electrolyte to carry the ions back and forth during charging and recharging).

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Planar Energy has developed a roll-to-roll process for making larger solid lithium-ion batteries. The company, which received $4 million in funding from the Advanced Research Projects Agency Energy program this spring, says it can print solid batteries that offer three times more storage than liquid lithium-ion batteries of the same size. This boost in energy storage is possible primarily because the company's all-solid batteries don't require many of the support structures and materials that take up space in conventional batteries, making more space for energy storage.

Planar Energy expects to reduce capital costs by half compared with solid-state battery manufacturing using high-vacuum machinery. And the company says its processes can be used to make cells big enough to power electric vehicles.

Comments

  • Amazing
    If that technology reaches the potential it says, it will be a breakthrough for portable electronics, and could even mean a shift of paradigm on transportation.

    It's speaking of 200 mah/g at 3-5v, being pessimistic and setting the voltage to that of current li-ion cells (3.7v), that means 3.5V * 1000g * 0.2A = 700Wh/kg.

    That's about 4.5 times the energy density of current li-ion batteries, or 3.8 times that of li-po batteries, so we're talking of a 4x increase on electric cars range, or a 4x decrease on solar UAV/planes battery weight, which would pass from being 1/4 of the plane's weight to a despreciable amount.
    Rate this comment: 12345

    gaspercat
    07/20/2010
    Posts:2
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    5/5
    • Re: Amazing
      Energy density looks great, but I did not see even ball park cost estimates in the article...except that it will be less than previous solid electrolite processes.
      Rate this comment: 12345

      tsvieps
      07/23/2010
      Posts:1
      • Re: Amazing
        This is a really great point!  Battery cost for transportation applications is a huge issue, and this is one of the compelling arguments for changing the battery materials processing paradigm along with its structure.  Planar is not using bulk powders of either electrode materials, but growing each active layer in situ from relatively low-cost precursors.  Using current cost estimates for commodity scale precursor materials, the models indicate that we can get under the $300/kWh mark and meet the DOE goals for battery costs.  Additional savings can be had because of the inherent safety of the solid-state format and their tolerance for abuse.  This simplifies the balance of system and further reduces the delivered cost of the battery.  How low can Planar go on the cost?  We don't know yet, but keeping the battery cost low is part of the optimization process.
        Rate this comment: 12345

        rolandpitt...
        07/26/2010
        Posts:6
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        5/5
    • Re: Amazing
      While your estimate is good for the specific energy of the cathode material, I would like to point out that inclusion of the other parts of the cell gives a more realistic value.  The design point for the prototype Planar cell, fully packaged, with a capacity of 5 Ah, is a specific energy of a little over 400 Wh/kg.  The energy density of this cell is a little over 1200 Wh/l.  Larger cells will yield numbers that are improved a bit.  These numbers are not as high as your estimate, but are still substantial improvements over current, high-end Li-ion cells.  We anticipate having these cells in durability testing in less than a year.
      Rate this comment: 12345

      rolandpitt...
      07/25/2010
      Posts:6
      Avg Rating:
      5/5
  • Longevity?
    I wonder what the longevity will be in service and if there are any heating effects to worry about? looks like they have an impressive solution, I will follow with interest
    Rate this comment: 12345

    Viv
    07/20/2010
    Posts:29
    Avg Rating:
    4/5
    • Re: Longevity?
      Very good question, since there are very high energy cells that operate only for a few cycles!  The Planar cell design is based upon all solid-state, inorganic materials with high stability windows.  We anticipate shelf and cyclic lifetimes similar to the thin film batteries, and thermal tolerance that is better than current Li-ion batteries.  The packaging materials may turn out to be the limitation on thermal tolerance.  It is worth noting that if our efforts to minimize the interfacial impedance between the active materials are successful, internal heat generation will not be a significant issue, even at high C-rates.
      Rate this comment: 12345

      rolandpitt...
      07/25/2010
      Posts:6
      Avg Rating:
      5/5
  • Lithium Sulfur
    If planar can adapt this technology to Lithium Sulfur battery chemistry, we could end up seeing even higher energy densities than with the Lithium-Ion chemistry.
    Rate this comment: 12345

    honzik
    07/20/2010
    Posts:14
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    4/5
    • Re: Lithium Sulfur
      Sulfur looks interesting, the voltage is a little lower, the capacity may be quite large.  Cyclic stability appears to be one of the main issues with using sulfur as a cathode.  There are some interesting ideas out there about how to stabilize sulfur, so if these appear to be working, Planar will take a hard look at going this route.
      Rate this comment: 12345

      rolandpitt...
      07/26/2010
      Posts:6
      Avg Rating:
      5/5
  • Charge times
    How fast can this battery be charged up?
    For cars people are used to 5 - 10 min to gas up...

    8 hours seems too long to me.

    Could you quick charge a Super-Capacitor at a charging station ("Go get a Charge at the Station") and have the SP charge the battery.
    SPs have quick charging times. The SP sounds good for recapturing Braking energy in Transportation uses also.

    For comparison most cars go 300 miles on a tank of gas.  300 Miles doesn't seem an impossible goal for an electric.

    If you don't charge up on the road what will happen to all the "mom and pop gas stations?" About one on every corner...
    Rate this comment: 12345

    geoff
    07/25/2010
    Posts:4
    Avg Rating:
    3/5
  • Longer-Lasting Auto Batteries
    Great thing to do but please try to make them in the USA, not China.
    Rate this comment: 12345

    paulinnr
    07/26/2010
    Posts:10
    Avg Rating:
    4/5
  • Charge Times
    Planar's experience with solid-state, thin film batteries indicates that the materials can be pushed pretty hard without damaging them.  However, as we make the electrodes thicker and higher capacity, there may be some limitations.  There is a balance between providing higher charge and discharge rates and keeping the capacity of the battery high, so there will be some trade-offs that will have to be made.  Batteries for some applications may be designed a little different than for others.  The use of supercapacitors on the front end of the battery may be required for some applications, not for others.  For transportation applications, a battery for hybrid vehicles may benefit from a supercapacitor front end.  A massive battery that provides long ranges in all-electric mode may need less.  Planar's solid state batteries have different operating characteristics than Li-ion batteries and may not require as much current management on the front end, but that also depends upon size.  Cost is also one of the considerations.  The final configurations will be the result of a lot of testing and optimization.
    Rate this comment: 12345

    rolandpitt...
    07/26/2010
    Posts:6
    Avg Rating:
    5/5
  • 4 Million and we are a step closer to a better battery!
    Makes one wonder if the companies and government actually wanted alternate energy how easy it would be.

    If 4 Million gets us that far, think how much 400Billion that the criminals gave to the banks would have brought the world.
    Rate this comment: 12345

    RealityBit...
    07/26/2010
    Posts:2
    Avg Rating:
    1/5
  • Share technology to make world gains
    I am happy to hear that printing methods can be applied to this medium and that it promises a three fold increase in capacity, but I have also read that a carbon nanostructure could add many times the storage capacity also, and it seems that I keep hearing of new advancements in a particular area of lithium battery technology that are independant of each other.  If we could all apply our own ideas and put them together to make one good battery it sounds like it would be forty or fifty times better through the sums of our boastings.  I expect good things to come in the next year, but hate to hear that it will take five to ten years to flesh these ideas out into a marketable battery.  We need to get together on these and get this out sooner.  Or do we want to burn up every last drop of oil first?  Keep up the good work fellas.  Just out of curiosity has anyone applied iron sulfide as a stable cathode? And what about tungsten coatings? Can we join laser sintering in there for that, create a rough micro surface in printing?  Just thinking on screen here.
    Rate this comment: 12345

    inventive4...
    07/28/2010
    Posts:2
    Avg Rating:
    3/5

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