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Ultracaps Could Boost Hybrid Efficiency

Recent studies point to the potential of ultracapacitors to augment conventional batteries.

By Kevin Bullis

Thursday, August 20, 2009

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Energy storage devices called ultracapacitors could lower the cost of the battery packs in plug-in hybrid vehicles by hundreds or even thousands of dollars by cutting the size of the packs in half, according to estimates by researchers at Argonne National Laboratory in Argonne, IL. Ultracapacitors could also dramatically improve the efficiency of another class of hybrid vehicle that uses small electric motors, called microhybrids, according to a recent study from the University of California, Davis.

Rugged power: This ultracapacitor is being used to capture energy from the brakes in hybrid buses. Similar devices could soon be used to reduce the cost of hybrid cars.
Credit: Maxwell Technologies

The use of ultracapacitors in hybrids isn't a new idea. But the falling cost of making these devices and improvements to the electronics needed to regulate their power output and coordinate their interaction with batteries could soon make them more practical, says Theodore Bohn, a researcher at Argonne's Advanced Powertrain Research Facility.

Although batteries have improved significantly in recent years, the cost of making them is the main the reason why hybrids cost thousands of dollars more than conventional vehicles. This is especially true of plug-in hybrids, which rely on large battery packs to supply all or most of the power during short trips. Battery packs are expensive in part because they degrade over time and, to compensate for this, automakers oversize them to ensure that they can provide enough power even after 10 years of use in a vehicle.

Ultracapacitors offer a way to extend the life of a hybrid vehicle's power source, reducing the need to oversize its battery packs. Unlike batteries, ultracapacitors don't rely on chemical reactions to store energy, and they don't degrade significantly over the life of a car, even when they are charged and discharged in very intense bursts that can damage batteries. The drawback is that they store much less energy than batteries--typically, an order of magnitude less. If, however, ultracapacitors were paired with batteries, they could protect batteries from intense bursts of power, Bohn says, such as those needed for acceleration, thereby extending the life of the batteries. Ultracapacitors could also ensure that the car can accelerate just as well at the end of its life as at the beginning.

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Reducing the size of a vehicle's battery pack by 25 percent could save about $2,500, Bohn estimates. The ultracapacitors and electronics needed to coordinate them with the batteries could cost between $500 and $1,000, resulting in hundreds of dollars of net savings.

Ultracapacitors would also make it possible to redesign batteries to hold more energy. There is typically a tradeoff between how fast batteries can be charged and discharged and how much total energy they can store. That's true in part because designing a battery to discharge quickly requires using very thin electrodes stacked in many layers. Each layer must be separated by supporting materials that take up space in the battery but don't store any energy. The more layers used, the more supporting materials are needed and the less energy can be stored in the battery. Paired with ultracapacitors, batteries wouldn't need to deliver bursts of power and so could be made with just a few layers of very thick electrodes, reducing the amount of supporting material needed. That could make it possible to store twice as much energy in the same space, Bohn says.

Comments

  • Hybrids and Ultra Capacitor Research
    Kevin,

    The researchers who are doing the work with Ultra Capacitors had better wake up or they are going to come in to the lab some morning and find out that the research has already been done and they are out of work .
    The time when a lifetime could be spent doing the same research over and over is past and research on Ultra Capacitors and Hybrid drive has been going on for years already .
    It is already known that a 600 cc gen-set and regenerative breaking with power stored in Ultra Capacitors is the next method of storing power for Hybrid Electric Vehicles and batteries will only be used for Pure Electric Vehicles .
    It is also known that Ultra Capacitors used in Pure Electric Vehicles will extend the life and remove stress from the batteries .In Extended Range Electric Vehicles like the GM Volt they would make it possible to have a smaller battery pack and could sell the cars for thousands less with a very robust drive from the capacitors .
    Apparently they (GM) are saving that for the next "new" development in version two of the Volt.
    Rate this comment: 12345

    Keith Tomils...
    08/20/2009
    Posts:9
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  • Ultrabattery
    CSIRO is Australia's premier research organization and has been testing Ultracapacitors combined with conventional batteries for years now.
    http://www.csiro.au/science/Ultra-Battery.html
    Rate this comment: 12345

    johnrerrey
    08/20/2009
    Posts:2
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    • Re: Ultrabattery
      Ahh yes, and I hear its going into commerical production with a Japanese battery manufacturer, but it isn't leading edge ('only' lead acid) , so it doesn't excite the most of the industry ..... sad, isn't it. The industry seems to strive for complexity and complicated solutions, rather than simplicity, so we have cars with over 1000 litium ion batteries joined together....
      Rate this comment: 12345

      bsperka
      08/20/2009
      Posts:2
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      3/5
  • also smaller engines
    Another advantage of an ultracapacitor in a microhybrid is that a much smaller (maybe 1/3 less), lower cost engine can pair with it. Much of the horsepower in our car engines is used only when we need short bursts of acceleration.

    Nice article.
    Rate this comment: 12345

    gametheoryma...
    08/20/2009
    Posts:18
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  • Help w/battery supply
    The reduced size of the battery could help offset the reported short supply of lithium.

    I also like the idea of Ultracaps combined with the inexpesively produced proven technology of the lead acid battery...It would make all those wind turbine farms that are being stood up to be a more consistent supply of energy rather than just when the wind blows.
    Rate this comment: 12345

    mike.horak@n...
    08/20/2009
    Posts:3
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  • Other technology also - It's the economics!
    Ultracaps might be useful in a mixed-technology battery pack, but other technologies might be used as well, e.g. Lithium Phosphate/Titanate (A123/Enerdel), or even the old fashioned NiMH. It really comes down to economics. Right now, the price for ultracaps is pretty high. It's really appropriate to plug in some actual numbers. Of course an ultracap could be used, but is an alternative technology cheaper and/or better in weight/volume?

    It turns out, that both old-fashioned NiMH and the newer Li batteries are better in cost, size, and weight than the current ultracapacitor modules (pictured).

    I don't have a price for the Maxwell Technologies module shown, but 47 of the cells it uses costs $6000, and the module is rated a little under 20kW continuous. That's about $300-400/kWc though about $60/kWp for 1-s peak. (300W/kg 200W/l) Compare that to LiFePO4 at $130/kW, 1200W/kg-- the batteries used in Prius plug-in kits and to be used in the Volt are cheaper/W and higher power/kg.

    Compare the ultracap module to the old-fashioned ordinary Prius battery. Each of the 28 individual modules (not the pack) are rated at 1300W/kg and about $30/kWp (I don't remember where I got the price/module.) The pack is rated at about 20kW (not the derived 37kW), so this comes out to be ~$60/kWc. So the <20kW ultracap pack is >$6K and weighs 60kg, but the old-tech Prius (2004-9) >20kW pack is >$1K at 45kg. The Prius battery is better and cheaper than the ultracap!

    Maybe in the future, ultracaps might be much less expensive-- it's just another possibility. EEStor's promised nirvana relies on increasing the voltage, but we have to wait and see what they can actually do. In the mean time, new generations of Li batteries (e.g. with Si nanomaterial as reported here) could also come along with lower cost, high power and life.

    The Tesla needs $30K of Li-Co batteries to get the 50kW power, and that also gives the >200mi range. By adding a Prius pack (or LiPO4), then only a $20K battery system would be needed at half the range, or maybe $15K at a third of the range. The plug-ins like Fisker & Volt just use the straight high-power Li phosphate/titanate, but presumably a more complex combination with the LiCo (used in the Tesla & laptops) would be lower in cost, higher in range. The main problem with the traditional LiCo is the lifetime of 500x cycles-- expensive compared to the >5000x new Li.
    Rate this comment: 12345

    carlhage
    08/20/2009
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    • Re: Other technology also - It's the economics!
      Hi--

      I think your comparison of battery to ultracap is missing the point. We all know batteries have more juice for $. But consider the cost of the life-time of the product and we have a different story. Ultracaps last a long time, and can be used as power buffers to extend the life time of the battery pack too. Calcutate the total cost over the life time of the vehicle and you will see there is a significant savings.
      Rate this comment: 12345

      trans
      08/22/2009
      Posts:5
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      4/5

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