Waste materials: Recycling worn-out batteries from electric cars produces a mix of finely shredded metals, consisting of cobalt, aluminum, nickel, and copper (show on the left), and a slurry that is processed into a cobalt cake (on the right).
Tesla Motors

Energy

Lithium Battery Recycling Gets a Boost

The DOE funds a company that recycles plug-in vehicle batteries.

  • Wednesday, August 12, 2009
  • By Tyler Hamilton

The US Department of Energy has granted $9.5 million to a company in California that plans to build America's first recycling facility for lithium-ion vehicle batteries.

Anaheim-based Toxco says it will use the funds to expand an existing facility in Lancaster, OH, that already recycles the lead-acid and nickel-metal hydride batteries used in today's hybrid-electric vehicles.

There is currently little economic need to recycle lithium-ion batteries. Most batteries contain only small amounts of lithium carbonate as a percentage of weight and the material is relatively inexpensive compared to most other metals.

But experts say that having a recycling infrastructure in place will ease concerns that the adoption of vehicles that use lithium-ion batteries could lead to a shortage of lithium carbonate and a dependence on countries such as China, Russia, and Bolivia, which control the bulk of global lithium reserves. "Right now it hardly pays to recycle lithium, but if demand increases and there are large supplies of used material, the situation could change," says Linda Gaines, a researcher at the Argonne National Laboratory's Transportation Technology R&D Center.

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Toxco's DOE grant may seem like pocket change--last week the DOE awarded a total of $2.4 billion to companies developing batteries and systems for electric vehicles--but it's also early days for the project. Sales of plug-in hybrids and all-electric vehicles have yet to take off, and though President Barack Obama has pledged to get a million plug-in hybrids on US roads by 2015, it will likely be a decade before any large-scale recycling capability is required.

Demonstrating the capacity to recycle, however, will be key to showing that electric vehicles are truly "green"--both emission-free in operation and sustainable in design. "Management of these batteries has to be done in an environmentally responsible way and in an economic way," says Todd Coy, executive vice president of Kinsbursky Brothers, Toxco's parent company.

Toxco also has an edge over newcomers to the market. The company is already North America's leading battery recycler and has been recycling single-charge and rechargeable lithium batteries used in electronics devices and industrial applications since 1992 at its Canadian facility in Trail, British Columbia. "We're managing the bulk of the batteries already out there," says Coy.

The Trail facility is also the only one in the world that can handle different sizes and chemistries of lithium batteries. When old batteries arrive they go into a hammer mill and are shredded, allowing components made of aluminum, cooper, and steel to be separated easily. Larger batteries that might still hold a charge are cryogenically frozen with liquid nitrogen before being hammered and shredded; at -325 degrees Fahrenheit, the reactivity of the cells is reduced to zero. Lithium is then extracted by flooding the battery chambers in a caustic bath that dissolves lithium salts, which are filtered out and used to produce lithium carbonate. The remaining sludge is processed to recover cobalt, which is used to make battery electrodes. About 95 percent of the process is completely automated.

The DOE grant will help Toxco transfer the Trail recycling process to its Ohio operations, laying the foundation for an advanced lithium-battery recycling plant that can expand to accommodate expected growth in the US electric-vehicle market. The electric-car maker Tesla Motors, like most major automakers, already sends old or defective battery packs to Toxco's Trail facility for recycling. "It's very important for us," says Kurt Kelty, director of energy storage technologies at Tesla. "The recycling issue is a key issue and we need to get it right."

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trans

42 Comments

  • 910 Days Ago
  • 08/12/2009

Ultracapcitors

A little more help... putting ultra-capacitors in front of the L-Ion batteries will extend the the life-time of the batteries. ultra-capacitors are also very good as reclaiming power from regenerative braking.

Reply

mkogrady

423 Comments

  • 910 Days Ago
  • 08/12/2009

Strategic Lithium Reserve

The recovered lithium salts apparently have little value compared to other types of metals used in batteries. However, like Petroleum, we may eventually see some type of risk associated with the continued reliance on the stuff.

Does it make sense to start up a Strategic Lithium Reserve that the US can then use to stockpile this material in the event of some unforeseen shortage or is it cheaper to start thinking of a battery type that uses alternate material to avoid a shortage all together - preferably with a material we have in our own back yard and don't have to import or be held hostage to later?

Reply

erbium

338 Comments

  • 907 Days Ago
  • 08/15/2009

Re: Strategic Lithium Reserve

Ha ha !!

the strategic petroleum reserve has little more than symbolic political use.   stupid politicians actually listen to dorks who clamber for piping it out when prices go up instead of waiting for a real emergency. 

Also if the gov't gets involved, the total costs will far outweigh any gain in paying slight increases that stimulate more production if supplies get tight.  Plus giving jobs to political cronies whose only qualification is 'raising palamino ponies' like the disgraced fema head.

it's a global economy.
Maybe they'd be less revolting in Bolivia (I mean have less revolutions) if they got some income.

The other funny thing is the 'xx years supply' available of lithium claims.  The point of you having 15 years supply doesn't mean that you will actually run out in 15 years, it means that if there ARE 15 years supply it doesn't pay to go dig up or look for more. 

Petroleum has been this way for a century.  Of course we have now reached the 'peak petroleum' where supplies are dwindling and there are no more easy to get supplies.  Opec countries like the saudis, after pumping heavily for 40 years or more, still claim the original or even more reserves, which can't be verified since no one from outside the country works for their oil company's offices. 

Russia and mexico has been using their oil fields as a national cash cow, without investing in infrastructure to ramp up declining production (mexico will become a net importer of oil shortly and their bloated pemex payroll and theft of investment money by the central government mean output is dropping 16% yearly in some fields)

and hugo's venezuela has kicked out talented oil engineers because they didn't vote for him, and nationalized much of the oil infrastructure, leading to more declines in the hard to get heavy crude, besides stupidly subsidizing gasoline at 29 cents per gallon. 

And if politicians are stupid enuf to tax away all the money big oil makes then they won't explore or dig up more.  Of course we still need to get heavily into alternative energy sources.

unlike petroleum, we haven't been digging up lithium in large amounts for a century.


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ms

190 Comments

  • 910 Days Ago
  • 08/12/2009

price comparison

Quoting the price of cobalt metal vs lithium carbonate doesn't seem like a fair comparison. After all, lithium carbonate is less than 20% lithium by weight. On the other hand, a given weight of lithium has 8.5 times as many atoms as the same weight of cobalt.

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seamountie

19 Comments

  • 910 Days Ago
  • 08/12/2009

Recycling and Bailout Package

I thought that the US bailout money was only to be used to "Buy American".  But I guess that only applies to Canadian goods, not Canadian companies.

"Holy Hypocrisy, Batman, the Americans can't even live by their OWN rules."

Reply

Mike bell

1 Comment

  • 892 Days Ago
  • 08/30/2009

Batteries

Hi,

Thanks for writing such an interesting article. Its really good to know about the batteries in detail. Seriously do we realize how many things in your house that need batteries? Let’s count it, from the flashlight, cell phone, iPod, cameras, and many more. Knowing it should make us realize on how essential the presence of the batteries in our daily life. However, with that so many kinds of battery, which is generally different between one to another, sometimes we have some difficulties in finding the desired type.

Find the right batteries supplier is not hard if you check out batterystation.co.uk because this website provides the widest selection of batteries and you can choose the right battery based on the categories. You can get the procell batteries which available in several sizes and voltage. You also can find Duracell batteries that divided into duracell plus batteries and duracell ultra batteries. All of the batteries come with cheaper price because this website provides the discount batteries in bulk, wholesale, and retail quantities.

Thanks,
Mike Bell

Reply

chenming717

1 Comment

  • 489 Days Ago
  • 10/07/2010

I need your help

??!
I'm a Chinese student and wangt to know something about recycling of lithium-ion secondary batteries. I think you are a expert.  Can you gave me some review paper. Thank you very much. My  mailbox is chenming1218717@163.com
Thank you again.

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