Energy

Revisiting Lithium-Sulfur Batteries

(Page 2 of 2)

  • Friday, May 22, 2009
  • By Kevin Bullis

In terms of addressing safety issues, three advances could account for Weber's confidence. Methods of chemically treating lithium metal electrodes can prevent at least some dendrite formation, although not all researchers are convinced that this approach will be sufficient. Also, improved polymer and ceramic membranes that separate the two electrodes and resist being pierced by the dendrites could prevent short circuits. The batteries, however, could still be vulnerable to short circuit if they're damaged. To prevent electrolyte fires, Nazar says that less volatile electrolytes could be used with lithium-sulfur batteries because they have lower voltage than lithium-ion batteries.

Other issues, including low conductivity and a limited number of recharge cycles, seem to have been addressed at least in part by Sion Power. The company has produced cells that store more than twice as much energy as lithium-ion batteries available today, something BASF hopes to improve. And Weber says that the batteries can last the lifetime of a car, although this may be based on projections from Sion Power, rather than measured performance.

John Kopera, Sion Power's director of commercial operations, says that the company's current batteries are rated for 50 cycles, and that it has a "comprehensive plan" to reach about 1,000 cycles. (That's enough for as much as 300,000 miles of driving, with a battery pack that provides a 300-mile range.)

Both companies are keeping details of their advances to themselves. But this week, in the journal Nature Materials, Nazar described one possible approach to solving these problems. In the past, researchers have improved conductivity by combining sulfur with carbon. Nazar went a step further by taking electrodes composed of regularly spaced carbon tubes and making them just a few nanometers wide. (Their structure is different from that of carbon nanotubes.) Nazar's team then packed sulfur into the nanoscale spaces between these tubes, so that most of the sulfur atoms sit close to conductive carbon, making them accessible to both electrons and lithium ions.

The carbon tubes also helped solve the issue of polysulfides, which can kill a cell prematurely. The carbon tubes effectively trap the polysulfides in place until they are fully converted to dilithium sulfide, which does not poison the battery. Coating the carbon with a polymer that has an affinity for polysulfides also helps keep them in place. But it's not clear whether BASF might also try a nanostructured electrode to improve Sion's materials. So far, Sion Power has not used nanostructured materials, Kopera says. One challenge with Nazar's approach is that it will be difficult to manufacture the carbon tube electrodes in high volumes.

Some issues likely remain. For one thing, the batteries may be costly--lithium metal is the most expensive form of lithium. Also, firm data isn't yet available on how many recharge cycles the batteries can undergo and how they respond to safety tests. Still, Nazar says, the technology has "certainly come a long way. Our developments and those of a couple of other companies are certainly enabling it to be much closer to reality."

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killian

74 Comments

  • 997 Days Ago
  • 05/22/2009

good article

Thanks Kevin. I have seen a number of Lithium Sulfur articles so far, and this was the first one that discussed the issues in such detail. It helps to have specifics though, and so I would add that GreenCarCongress gave Sion's specific energy as "more than 350 Wh/kg", and they had some nice charts.

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Kevin Bullis

178 Comments

  • 997 Days Ago
  • 05/22/2009

Re: good article

Thanks Killian.  I can confirm that number, 350 Wh/Kg is correct for Sion's prototype cell. But that only gets 50 cycles, so in some ways comparing that to lithium ion is apples and oranges.

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dancrissco

54 Comments

  • 801 Days Ago
  • 12/04/2009

Looks like a perfect battery for the pemmPOD

I have been looking for a perfect battery for the pemmPOD. (Personal Emotional Mobile)
This looks like an ideal candidate.
More details on the pemmPOD can be found at
http://dancrissco.wordpress.com/
The pemmPOD is a Solar experimental under concept design. It is configurable like a PC and serves as personal transportation, PC, media player and office work station. It is proposed to be made out of renewable materials.

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