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Reineke and his colleagues were able to get such good results because of several design modifications and refinements to their device. One involves reducing its operating voltage by doping the organic material that connects the light-emitting material to its metallic contacts. "The efficiency of the device is highly reduced if it is near a metal contact" because of a phenomenon called quenching, says Reineke.
Another trick was to make the outer surfaces of the device from types of glass that have optical properties that more closely match those of the device substrate. Otherwise, much of the emitted light is reflected and either reabsorbed or lost through heat. "In conventional structures, about 80 percent of the light is lost," says Reineke.
The most novel aspect of this new OLED, however, is the organization of different light-emitting materials within the device. Three materials are used--one each for emitting blue, green, and red light--along with a host matrix material in between. Reineke's trick was to choose a matrix material with a high "spin state" that matched that of the blue and to sandwich the blue material between the green and red, as if it were part of the separating host matrix material.
"The matrix and the blue state are nearly identical," Reineke says. This means that any electron-hole pairs (excitons) escaping the red or green material will have to pass through the blue, increasing the chances that they will be converted into photons.
"They do a nice job of tailoring the LED layers to get good quantum efficiencies," says Kazlas. "It shows the promise of OLEDs, but from an industry perspective, OLEDs still have a long way to go."
Indeed, a major drawback of OLEDs is their longevity. Although companies like Philips are able to make devices with life spans equivalent to fluorescent bulbs--in excess of 10,000 hours--materials that yield higher efficiencies tend not to last so long. "Our devices have lifetimes of just a few hours," says Reineke.
It's just a matter of time until the OLEDs get the same longevity as LEDs. But the question is if developing this technology is useful. I don't believe that the problem of the LEDs is that they emit blue light, at lest is not a big problem.
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if they are designed wrong.
they are particulary heat sensitive. in discussion of another article on this site a person had dissected a LED headlight after it failed, found it was designed wrong, and would blow out early no matter what.
if they overheat the semiconductor atoms which are loosely bound migrate and cause failure like letting your pentium run without a heat sink.
Philips has made a good job with his Lumibledes.Only commercial OLED light panel.
See here http://www.oledgadgets.com/oled-lighting.html.
I think that very soon we can expect more companies will have OLED lighting products.
Tremendous research is on on LEDs especially Organic. It is hoped they will revolutionalise lighting and will be affordable in developing countries.
Dr.A.Jagadeesh Nellore(AP),India
E-mail: anumakonda.jagadeesh@gmail.com
Manufacturing in the United States is in trouble. That's bad news not just for the country's economy but for the future of innovation.
javs
97 Comments
Disruptive Light?
"Our devices have lifetimes of just a few hours"
Disruptive technologies start like that. What are the posibilities to increase lifetimes? Will they compete with high efficiency and short life (i.e. 500 hrs.)? Could be! It is just a matter of having the economics right in a world of expensive energy.
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Guest (quatermass)
Re: Disruptive Light?
Surely they've solved the lifetime aspect of OLED?
Sony and Samsung already sell OLED TVs with a lifetime of 10,000+ hours.
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