Energy

Better Lithium-ion Batteries

(Page 2 of 2)

  • Friday, March 27, 2009
  • By Prachi Patel

The advantages of polymer materials have warranted research on polymer electrolytes for more than three decades. In fact, lithium polymer batteries are already found in radio-controlled cars and MP3 players. But they use a polymer gel containing solvents, so, like liquid electrolytes they carry the risks of fire or explosion and do not have a very long life.

Making solid polymers that are as conductive as liquid electrolytes has been difficult. In a charging battery, the electrolyte conducts lithium ions from the positive electrode, or cathode, to the anode. The higher the conductivity of the electrolyte, the faster the battery charges. St. Paul, MN-based 3M and Montreal, Canada-based electricity provider Hydro-Québec have spent more than 10 years on solid-polymer lithium batteries. "But you have to operate the polymer at 60 degrees Celsius to improve conductivity," Amine says. "This is not very practical."

The problem is that a polymer's conductivity and mechanical strength do not go hand-in-hand. "If people tried to make polymers with high ionic conductivity they would end up with a goop," Singh says.

Seeo has gotten around the problem by making films with block copolymers: materials containing two linked polymer chains that self-assemble into nanostructures. One of the polymers forms an array of conductive cylinders that are embedded within the other polymer, which serves as a hard matrix. Singh says the electrolyte film is robust and is almost as conductive as liquid electrolytes.

Seeo's technology "has become very attractive" because of its claim of a high-conductivity polymer, Amine says. However, "the lithium anode could be a show-stopper." Lithium has a tendency to get roughened at the surface and grow crystal dendrites that can reach the cathode and short the battery. The company will need to do long-term tests to show that its polymer is hard enough to block the dendrites.

Polymer electrolytes also have one big inherent disadvantage. "Polymers will always be limited by lower ionic conductivity compared to liquids," Singh says. This means that Seeo's battery would be limited for use in laptops and electric vehicles. "But these polymers wouldn't be able to address quick-charge applications like hybrid-electric vehicles or power tools."

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Keith Tomilson

9 Comments

  • 1053 Days Ago
  • 03/27/2009

More Information Needed

Do they need to be heated or cooled ?
How many volts per cell ?
How many amps per illustrated call ?
How much will they cost ?
When will they be mass produced ?
Where will they be made ?
Can anybody buy them now ?
Can I get them to make my own Electric car ?

Reply

ms

190 Comments

  • 1053 Days Ago
  • 03/27/2009

cathode vs anode

In a charging battery, the anode is the positive terminal and the cathode is the negative terminal. In a discharging battery, the anode is the negative terminal and the cathode is positive. Given how easily this can cause confusion, I suggest not using "anode" and "cathode", instead just "positive" and "negative".

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Keith Tomilson

9 Comments

  • 1053 Days Ago
  • 03/27/2009

Patent Infringement ?

It has already been done by a Canadian company .

The link to their home page is below .

Sorry guys , but before you "invent" something you should do a simple search to see if your idea is original . It is impossible to "invent" something that already exists .

http://www.electrovaya.com/innovation/other/pcd.aspx

Reply

nekote

139 Comments

  • 1053 Days Ago
  • 03/27/2009

Re: Patent Infringement ?

Didn't spot specific reference to *solid* electrolyte.

Could you be so kind as to point out a confirmatory link?
Possibly a specific patent?

Reply

clazy

2 Comments

  • 1049 Days Ago
  • 03/31/2009

Re: Patent Infringement ?

maybe this will help

Reply

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