Powered up: An amorphous layer (light-colored band at the right) on a crystalline battery material improves its performance.
Byoungwoo Kang, MIT

Energy

Ultra-High-Power Lithium-Ion Batteries

New materials from MIT could power laser weapons or give hybrid cars jackrabbit acceleration.

  • Wednesday, March 11, 2009
  • By Kevin Bullis

A lithium-ion battery electrode described this week in the journal Nature can deliver electricity several times faster than other such batteries. It could be particularly useful where rapid power bursts are needed, such as for laser weapons or hybrid race cars.

Test batteries based on the new electrode--developed by Gerbrand Ceder, a professor of materials science at MIT--can be discharged in 10 seconds. In comparison, the best high-power lithium-ion batteries today discharge in a minute and a half, and conventional lithium-ion batteries, such as those in laptops, can take hours to discharge. The new high rate, the researchers calculate, would allow a one-liter battery based on the material to deliver 25,000 watts, or enough power for about 20 vacuum cleaners.

This level of power output would put these batteries on par with ultracapacitors, gadgets that can rapidly discharge power but can't carry much energy for their size, says John Miller, a vice president for systems and applications at Maxwell Technologies, a manufacturer of ultracapacitors, who wasn't involved in the research. The new batteries would store nearly 10 times as much energy as an ultracapacitor of the same size. The combination of small size and extreme power could make the batteries particularly useful for race cars, he says. (Starting this year, new Formula One racing rules will allow race cars to store energy from braking to deliver very brief jolts of acceleration.)

To improve the batteries, the researchers modified an electrode material called lithium iron phosphate to allow electrons and ions to move in and out of it much more quickly. The advance is based on computer models that Ceder developed in 2004. The models suggested a way to improve conductivity by directing lithium ions toward particular faces of crystals within the material.

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To exploit this, Ceder included extra lithium and phosphorus. This helps form a layer of lithium diphosphate, a material known for its high lithium-ion conductivity. He says that ions encountering the material are quickly shuttled to faces that can pull them in, allowing for very fast discharging.

The fast-discharging materials may also recharge quickly, raising the possibility of cell phones that charge in seconds, Ceder says, but this would require expensive chargers. Ric Fulop, vice president of business development at A123 Systems, a battery maker based in Watertown, MA, that has licensed Ceder's new material, says that it could be useful for hybrids or for delivering the power needed for laser weapons. (Fulop notes that A123 is not developing batteries for the latter application.)

Other researchers have already modified lithium iron phosphate to achieve power levels high enough for power tools and for most hybrid vehicles. Indeed, iron phosphate batteries are already being sold by more than one battery maker for such applications. Ultimately, the energy capacity of lithium iron phosphate is lower than that of other lithium-ion battery materials, making Ceder's advance of limited value, says Jeff Dahn, a professor of physics at Dalhousie University, in Halifax, Nova Scotia. This battery is good for acceleration, but not as much for long range. "A real breakthrough . . . would be a new positive electrode material with quantum-leap performance specs" in energy storage, Dahn says.

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lasertekk

146 Comments

  • 1060 Days Ago
  • 03/11/2009

famous last words

'not developing batteries for laser weapons...'

Sure you're not.

Reply

Handshake

19 Comments

  • 1059 Days Ago
  • 03/12/2009

Grownd base...

I wander witch country will give, us, cheap  "Lithium-Ion" minerals?

HMmmm... Let me think...

Reply

johmar

1 Comment

  • 1059 Days Ago
  • 03/12/2009

For ever and ever

...would allow a one-liter battery based on the material to deliver 25,000 watts, or enough power for about 20 vacuum cleaners. ...
20 vacuum cleaners never running out of power? :P

Reply

Kevin Bullis

177 Comments

  • 1059 Days Ago
  • 03/12/2009

Re: For ever and ever

Well, more like 10 seconds. It's just an indication of how much power 25,000 watts is.

Reply

bipll

1 Comment

  • 1058 Days Ago
  • 03/13/2009

Re: For ever and ever

Never running out of vacuum. :O

Reply

WestfW

1 Comment

  • 1059 Days Ago
  • 03/12/2009

So how does this material compare to the "nano-structured" LiFePO4 material that A123 has been using for a while now?   Better?  Cheaper to manufacture?

Reply

Kevin Bullis

177 Comments

  • 1058 Days Ago
  • 03/13/2009

Re:

The rate's faster.  The minute and a half I site above is basically A123 (although others have achieved similar results in the lab).

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jmaximus9

86 Comments

  • 1057 Days Ago
  • 03/14/2009

What about the chargers?

You would need some pretty high output charging stations to charge the Chevy Volt's batteries in 30 seconds.  One has to wonder if the grid could even handle this kind of demand.  My house lights dim when I plug in the electric heater, I can only imagine what would happen if I plugged these super batteries in my garage.  Words like "blackout" come to mind.

Reply

jvanderbilt

2 Comments

  • 1055 Days Ago
  • 03/16/2009

That's where the smart grid comes in.

Everyone will get to charge their cars overnight. They'll charge sequentially throughout the neighborhood via grid synchronized chargers. Of course you will receive a preferential charging time if you are an Obama '12 bumper sticker.

Reply

craigk2

1 Comment

  • 1055 Days Ago
  • 03/16/2009

series-parallel solutions?

The advantages of quick charge-discharge in vehicles seem significant; particularly brake charging and traffic light acceleration. The potential problems associated with charger overload or less power density can easily be solved by putting an ultra power battery in parallel with the conventional Li-Ion battery and switching it on/off with power transistors (as needed for both charging and discharging).

Reply

Gaetano Marano

246 Comments

  • 1054 Days Ago
  • 03/17/2009

>>> with (also) this idea, the electric cars may happen SOON and the swappable batteries become completely unnecessary! >>>

.

as explained in the latest UPDATE of my "cellphoneCAR" article ...

http://www.gaetanomarano.it/articles/033cellphoneCAR.html

... the idea of "swappable batteries" for the electric cars will become soon COMPLETELY UNNECESSARY since the new, 100+ times faster to recharge/discharge, Li-Ion batteries and the, 100+ times electric charge, supercapacitors (to be available soon) may solve ALL the existing problems to build and sell electric cars!!!

.

Reply

Tysto

34 Comments

  • 1033 Days Ago
  • 04/07/2009

Re: >>> with (also) this idea, the electric cars may happen SOON and the swappable batteries become completely unnecessary! >>>

Oh good, because that idea was never very good. Even if you figure that people will mostly get their power by recharging at home overnight, every station near a popular venue (sports stadium, beach) would have to have dozens of batteries on hand *plus* a charger for every one of them. *And* the Tesla battery that gets 200 miles per charge weighs almost 1000 pounds.

Reply

thonycortes

1 Comment

  • 883 Days Ago
  • 09/04/2009

Ultra high power

If there one, I hope it's cheaper and can power a laptop within 10 hour or more..

Reply

PrincessAries

1 Comment

  • 281 Days Ago
  • 04/29/2011

Batteries

This si helpful but never lick a lithium battery.it hurts lmao..yes i've done it..sorry

Reply

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KSBHARADWAJ

1 Comment

  • 89 Days Ago
  • 11/07/2011

LI-ION BATTERIES

I think there should be international interest in Li-ion battery business in terms of cradle to grave solutions.

Reply

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