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Taking Pulp to the Pump

Continued from page 1

By Peter Fairley

Friday, December 12, 2008

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Rudberg says that Chemrec worked closely with researchers at Oak Ridge National Laboratory to identify appropriate materials for testing in a gasification plant that has operated at a Weyerhaeuser mill in New Bern, NC, since 1996. This plant can process up to 15 percent of the mill's black liquor. Rudberg says that the refractory at New Bern has been operating for two years, which he believes is long enough to prove that its commercialization is viable.

That performance is clearly enough to convince Chemrec's backers to finance the next step: generating biofuel from the syngas. While Weyerhaeuser simply burns the syngas to generate heat at New Bern, Chemrec's small research plant in Pitea, Sweden, has demonstrated production of syngas pure enough for catalytic fuel synthesis. BioDME, Chemrec's EU-funded consortium, will turn that syngas into between four and five metric tons of DME per day.

Another BioDME partner, Haldor Topsoe, will build the DME synthesis plant, to start up in 2010. Göteborg-based Volvo Group (not to be confused with the Ford-owned luxury-car division, Volvo Cars) will adapt the fuel systems of 14 long-haul diesel trucks to run on DME. And Swedish oil company Preem is building four fueling stations to distribute the DME across Sweden.

At the same time, Chemrec is doing the engineering for two plants that would be 25 times larger, producing 40,000 tons of DME each year: one at Pitea, and one at the New Page mill in Michigan. Converting every pulp mill in the United States would, according to Rudberg, generate the equivalent of about 7.5 billion gallons of fuel--about one-fifth of the U.S. government's total target for 2020.

But it remains questionable whether demand would naturally follow. DME is currently used primarily as a substitute in aerosol spray cans, and clearly more than four fueling stations in Sweden will be needed for it to take off as a biofuel. Marc Londo, a senior research and biofuels expert at the Energy Research Center of the Netherlands, in Amsterdam, says that this chicken-and-egg dilemma is a major drawback. He believes that Chemrec's success would be better assured if it produced synthetic diesel from its syngas--a strategy pursued by German biomass gasification innovator Choren Industries. "The strong advantage of synthetic diesel is you can simply blend it with currently available diesel," says Londo. "For bio DME, you need dedicated distribution networks."

Londo says that synthetic diesel has another advantage: while it costs slightly more to produce from syngas than DME does, synthetic diesel has a higher energy density. A tank of diesel will take a long-haul truck twice as far as a tank of DME: "For long-haul trucks, energy density is a critical factor, and synthetic diesel is thus a more valuable fuel," he says.

BioDME project leader Per Salomonsson, an R&D manager with Volvo Group, says that it comes down to how much fuel an acre of land will produce. Synthetic diesel would be a lot easier for Volvo Group to drop into its vehicles, but according to their estimates, DME will deliver over 65 percent more miles of travel per acre cultivated; compared with conventional biodiesel produced from vegetal oil, the advantage is five to one. "There will be a shortage of biomass in the future," says Salomonsson. "In the long run, we can't afford to have anything but the most efficient process."

Comments

  • Bio Oil
    This sounds like a wonderful feedstock for catalytic or thermal depolymerization (turn it into oil, diesel, naptha, gas and clean water.  Oil prices may be low today, but the price will climb back up soon enough.
    Rate this comment: 12345

    tsaidak
    12/12/2008
    Posts:15
    Avg Rating:
    4/5
  • good work
    Well done article, unlike the rewritten press releases often seen on this site.
    Rate this comment: 12345

    walt
    12/12/2008
    Posts:29
    Avg Rating:
    2/5
  • An Option Among Others
    Black liquor has obvious advantages. Because it is a byproduct of an industrial process, most of the costs and energy required to make it accrue to paper production. It currently is used to produce electricity rather efficiently, but a new option to co-produce electricity with some amount of synfuels might benefit the industry. As we've seen before, efforts to exploit low-hanging fruit can ultimately aid exploitation of more difficult feedstock. Maybe...

    In the end, 20% of 2020 diesel fuel becomes 15% of 2030 diesel fuel and so on as a limited resource looses ground against growing demand. And 20% of diesel fuel is quite a small part of overall oil consumption - less than 1%.

    What it comes down is this: either we cling to the internal combustion engine and watch the fuel dry up, or we propel our vehicles with electricity, which has vast untapped, domestic potential.

    Consider that the elimination of ALL oil demand for highway transportation by 2030 would (all other things being equal) leave us consuming 80% of what we now consume and importing at least 65% of what we would use. This is owing to projected increases in population and industrial output. We need to drastically reduce consumption of oil in all sectors in order to make large inroads toward self-sufficiency.

    Synfuels from coal and stranded natural gas have vastly greater potential than paper mill byproducts, but if it helps, then why not pursue it? In the end, though, we either stop using oil or we find a domestic source of renewable hydrocarbons with exceptional potential. Algal biodiesel may be the closest prospect to fill that role. Like all other technologies, there are great hurdles to overcome.
    Rate this comment: 12345

    MakeSense
    12/14/2008
    Posts:93
    Avg Rating:
    3/5
  • [no subject]
    Diesel exhaust tip after-treatment is an important concern in applications with high biofuels content, Biofuel mandates for gasoline engines are energy based; moving to a volume-based replacement will increase ethanol content by up to 50 per cent. This will reduce the specific power output, although OEMs are working towards sensor-based engine management systems to ensure minimal impact on driving characteristics.
    Rate this comment: 12345

    MickeyFouse
    04/02/2009
    Posts:47
    Avg Rating:
    1/5

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