Energy

Realizing Lithium-Battery Potential

(Page 2 of 2)

  • Wednesday, December 3, 2008
  • By Peter Fairley

The process for making the nanoporous silicon material also marks an improvement over methods for making previous silicon anodes, says Cho. To create the nanoporous anodes, the Korean researchers mix silica nanoparticles with a viscous gel of carbon-coated silicon (to keep the silicon and silica from reacting chemically), heat the mixture to 900 °C to fuse it into a solid mass, and then selectively etch away the silica with hydrofluoric acid to create the pores. In contrast to most silicon assembly methods, the process takes place at atmospheric pressure and thus should be easier to scale up to large volumes. "It's a much more economical process for mass production," says Cho.

Cho says that he hopes to sell the technology to Korean battery maker LG Chem, where he has worked for the past four years and which may have won the lithium-battery contract for GM's forthcoming Chevy Volt. But he could face competition. Cui says that his lab has also dramatically improved its nanowire synthesis and battery design, and in September, GM scientists presented impressive results on lithium anodes created using silicon-coated carbon fibers.

But the real question, say observers, is whether any of these materials can be produced at the right price. Marc Obrovac, a research specialist at 3M working on lithium-battery materials, points to a sophisticated silicon anode design already made by Sanyo Electric that achieves energy densities exceeding Cho's. "Despite this superior performance, Sanyo apparently never commercialized its silicon electrode," says Obrovac. "Fabrication cost may have been a factor."

Cui points to another factor that could limit the impact of silicon anodes: cathode performance. If new cathode materials could match the energy density of the silicon anodes, this would multiply the energy storage capacity of finished batteries four- or fivefold, he says. Using conventional cathodes, however, would require a sixfold increase in the cathode's mass and volume to deliver a doubling of the total energy storage. "We are actually limited more by the cathode," says Cui. "Improving the anode will have a very big impact. But improving the cathode can have an even larger impact."

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Larry McFarland

4 Comments

  • 1166 Days Ago
  • 12/05/2008

Lithium supply

Lithium is too costly to use for cars. The only place that it can be extracted economically is in Chili at $1200/ton. We have to pay $12K/ton to a dictator. There's enough there for approx 260K cars. Hardly enough to make it worth competing with batteries for hearing aids and cameras.

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TestPilot

13 Comments

  • 1165 Days Ago
  • 12/06/2008

Re: Lithium supply

Wholesale price per ton of Aluminum is around $3000. And price for Lithium only two and a half times higher. So Coca-Cola can made of Li instead of Al would cost roughly 6 cents instead of 3(Li even lighter then Al). And in fact, Lithium price is very similar to Copper. Per tonne.

But the real problem is that there a little demand for Lithium in everyday life or in industry. No demand - no offering. There huge potential for mining Lithium in China alone. And price of Lithium itself in Li-Ion batteries is so tiny, that it not worth mentioning. Just like price of silicon(read "sand") in solar cells is minor compare to whole production process. 

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techron

13 Comments

  • 1162 Days Ago
  • 12/09/2008

Re: Lithium supply

Is it realy that plentiful?

Is it just mined in Chili because of low demand??

Laptop and camera batteries have dwarfed hearing aid usage of the stuff.

There must be new mining ops coming on line like you infer. Where are these located?

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truera

2 Comments

  • 823 Days Ago
  • 11/13/2009

Re: Lithium supply

Your costs and prices for lithium are way out. The costs for production at Atacama are much higher than stated. On prices a quote from TRU -

Lithium Price Trend: Dominating lithium producer SQM in September 2009 announced 20% price reductions. Lithium prices have been flat through 2009 bolstered by the steep fall in the US dollar against lithium producer and user currencies. TRU president Edward R Anderson says “the SQM price reduction was a necessary correction and consistent with the TRU over-supply scenario. Indeed, there is little prospect for price volatility even long range. TRU projects an orderly and balanced development of the lithium industry through the 2020 horizon”.

TRU Group Inc based in Toronto, Canada and Tucson, USA are industrial management and engineering consultants with a strong capability in lithium project development.

http://trugroup.com/Lithium-Market-Conference.html

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doctorronald

1 Comment

  • 1116 Days Ago
  • 01/24/2009

conspiracy theories of the king of Saudia Arabia

There seems to be three times that majore breakthroughs have occured with this Silicon Lithium batteries 1) Yi Cui at Stanford, 2) Jaephil Cho in Korea, and 2) Sanyo.  I understand that the king of Soudia Arabia paid off Yi Cui with at least 10 million dollars; and, then, suddenly, there is no mention of him.  And I know that it sounds like paranoia and and I hate when people mention conspiracy theories; but, what if the king also paid of Sanyo? And then the question is will they also pay off Yi Cui?  If I were sitting on 1/4 of the oil supplie in the world, and, if I had billions of dollars at my disposal, and, if this silicon lithium breakthrough was going make Barack Obama's vision come true - lose the dependence off of forieng oil, then I would gladly pay what it takes.  And, if I were a PHD assistant professor and offered $10 million, and, if I were a company like Sanyo and given a few $100 million, and, if I were Jaephil Cho and given 10 million dollars to bury this information, I would easly take it.

My apologies: there is already a very heated and thorough debat blog at http://www.autobloggreen.com/2008/04/13/saudis-invest-in-silicon-nanowires-trying-to-bury-battery-break/#comments

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