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Light trap: Treating silicon with short, intense femtosecond laser pulses in the presence of sulfur creates tiny cones on its surface. The rough, sulfur-infused surface is an excellent light trap, capturing nearly all of the sun’s light, including the parts of the spectrum that pass through normal silicon.
SiOnyx
A new type of silicon promises cheaper, more-sensitive light detectors.
Silicon's ability to absorb light and produce electric current has made it the material of choice for light sensors and solar cells. Yet about half of the light from the sun--red light and most of the infrared--passes right through silicon.
SiOnyx, a startup based in Beverly, MA, is making a new type of silicon material, dubbed black silicon, which captures nearly all of the sun's light. "It is basically a sponge for light, both visible and infrared," says CEO Stephen Saylor. The material uses the light more effectively, generating hundreds of times more current than conventional silicon. The company, which has licensed technology developed at Harvard University, also claims that the material makes it possible to use less silicon for light sensors, making the devices cheaper, smaller, and lighter.
Saylor says that the highly sensitive light detectors made from black silicon would have many advantages. In medical x-ray imaging, he says, "if you have a very high-sensitivity detector, you could lower the radiation dose of x-rays to get that image." Because the detectors pick up extremely low light signals, they could be used for in vitro imaging, night-vision goggles, and light sensors in digital cameras. Low-light applications currently use more exotic and expensive gallium arsenide.
The material could also be used to make infrared detectors, a new application for silicon. Infrared detectors, used in fiber-optic telecommunications, astronomy, and security systems, are made of gallium arsenide and other materials that are difficult and expensive to process in addition to containing toxic chemicals such as lead and mercury. "Black silicon extends the technology that we know extremely well and makes it usable in a region of spectrum where it wasn't useful before," says Eric Mazur, a professor of applied physics at Harvard, who discovered the material in his lab. "I really believe it's a new class of materials, just as semiconductors were a new class of materials 60 years ago." Mazur cofounded SiOnyx in 2006 with his then graduate student James Carey, now the company's chief science officer.
The company makes the material by putting conventional silicon in a chamber full of sulfur hexafluoride gas and bombarding it with short, intense pulses from a femtosecond laser. This roughens the surface by creating millions of tiny cones on it. The rough layer is about 300 nanometers thick and infused with sulfur atoms.
This thin surface layer does all the light capturing. Conventional silicon devices use 0.5-millimeter-thick silicon. Black-silicon devices would use hundreds of times less silicon, which would cut costs, Saylor points out. The thin devices would also be easier to incorporate into an integrated circuit.
On reflection to what I just read this is the solution that can be effected now.
Stack a normal "clear" silicon cell on top of the black silicon. If visual light in not utilized by the black and the clear silicon utilizes all forms of light other then IR and higher, it seems pretty strait forward what to do. Layer the cells and to uses exsisting tech; one clear, one black, a true 100% cell
The hype here is rather extravagantly outreaching the actual physics. I notice that these people do not claim to have made a solar cell from their material, and for good reason.
In a good silicon cell manufactured with today's technology, the absorption of light in the wavelength band usable by silicon is already well above 90%. You cannot possibly produce "hundreds of times more current" in a solar cell; this is physically nonsensical.
It is true that silicon solar cells do not respond to infrared longer than about 1.1 microns wavelength. This portion of the solar spectrum contains about a third of the energy in sunlight. However, these infrared photons have too little energy to create electron/hole pairs. Increasing the absorption of these photons by the silicon isn't going to help; silicon can not make use of the energy of the photons because its bandgap is too wide. If you narrow the bandgap, you can absorb these photons-- but at the price of decreasing the available voltage. (And, in any case, you couldn't increase the current by "hundreds of times" even if you drop the output voltage to zero.)
hey, it has been a while since you wrote your comment but only now i started to show interest in the technology.
i would love if you can send me a reference to solar cell that uses well over 90% of the light.
as far as i know the commercial solar cells are abou 10-20% and the highest any one got is about 60% with a very expencive technology in one of the US univercities. (i also know that in weitzman Institute in IL they got about 40% few years ago.
since my research is about solar cells implemintation i would love to get a refernce to these cells you mentioned.
thanks in advance,
gil.
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2 Comments
Black Silicon
This material sounds promising, and could possibly approach a true black body absorber. For example electrical tape absorbs infrared quite well, no matter the visible color. Cavities absorb infraed even better but not the visible spectrum unless they are the correct size corresponding to whe wavelength. The conical nature of the cavities formed by this material should make it a broad band absorber. By electricaly isolating the cavites so formed one from another, an efficient broad band photo-detector or photo cell is produced depending on the way they are reconnected or scanned.
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