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Nanoflower power: A transmission electron microscope image shows a flowerlike manganese oxide nanoparticle deposited at the junction of crossed carbon nanotubes. Used as an electrode material, this nanotube-manganese-oxide composite could improve the energy-storage ability of ultracapacitors, which show promise as powerful, long-lasting replacements for batteries.
American Chemical Society
A novel design could boost energy storage.
Imagine a cell-phone battery that recharges in a few seconds and that you would never have to replace. That's the promise of energy-storage devices known as ultracapacitors, but at present, they can store only about 5 percent as much energy as lithium-ion batteries. An advance by researchers at the Research Institute of Chemical Defense, in China, could boost ultracapacitors' ability to store energy.
A capacitor consists of two electrodes with opposite charges, often separated by an insulator that keeps electrons from jumping directly between them. The researchers have developed an electrode that can store twice as much charge as the activated-carbon electrodes used in current ultracapacitors. The new electrode contains flower-shaped manganese oxide nanoparticles deposited on vertically grown carbon nanotubes.
The electrodes deliver five times as much power as activated-carbon electrodes, says Hao Zhang, lead author of the Nano Letters paper describing the new work. The electrode's longevity also compares with that of activated-carbon electrodes, Zhang says: discharging and recharging the electrodes 20,000 times reduced the capacitor's energy-storage capacity by only 3 percent.
In a typical ultracapacitor, two aluminum electrodes are suspended in an electrolyte. A voltage applied to the electrodes separates the positive and negative ions in the electrolyte, which get attracted to the oppositely charged electrodes. How much energy the ultracapacitor can store largely depends on the electrodes' surface area: the more area, the more space to store charge. Coating the electrodes with activated carbon increases their surface area, since a teaspoonful of the porous, spongelike material has about the surface area of a football field. Ultracapacitors can store millions of times more energy than the tiny capacitors used in electronic circuits.
But their performance still pales beside that of batteries, which store energy using chemical reactions. "If I gave you a cell phone with an ultracapacitor battery, you'd never replace the battery, and you could recharge it in a few seconds, but it would only last half an hour," says Joel Schindall, an electrical-engineering professor at MIT.
So far, ultracapacitors have been limited to niche applications that require high power and quick, repetitive recharging. For example, the devices provide quick bursts of power to buses, trucks, and light-rail trains over short stretches, and braking replenishes them. If they could store more energy, however, they could be a powerful, long-lasting replacement for batteries in hybrid-electric vehicles and portable electronics.
Vulvox Nanobiotechnology Inc. has a similar concept on the drawing board; we call them itchy balls since they resemble horse chestnuts with hundreds of seeds sticking out from each itchy ball. Our materials science page details some of our work on super-capacitors. Briefly, a carbon nanotube adhesive material we discovered has very high porosity and conductivity. Itchy balls are analogous to nanoflowers and they can be used to store electricity in supercapacitors
Http//vulvox.tripod.com
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6 Comments
The Future
These ultra capacitors are something I think will revolutionize all of electronics. I also believe that these things will be the essential element needed to bring about electric cars for everyone. The idea that they can be charged almost instantly fits right in with the driver mindset of needing to periodically refill anyway.
In the electronics world, we need powerful storage in very small packages. Those of us who've seen Lethal Weapon 1 remembers Mel Gibson standing on a freeway overpass holding a cellphone with a huge battery pack. These days we have cellphones that make a deck of cards feel obese. The small internal storage space provided, given the form factor, is screaming for ultra capacitors as lithium-ion batteries are being pushed to their limits. Being able to charge quickly is the thing I find most beneficial here. Imagine charging up your cellphone in less than a minute! As these things begin to hold significantly more power we'll be able to get through a day on a single charge. Even if it's only a half a day, does it really inconvenience all that much if it takes us two minutes to charge it back up? Most of us take several breaks throughout the day anyway.
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YankeeBruce
21 Comments
Re: The Future
This future has been around for at least 20 years.
The promise is bright, but the challenges are difficult. This technology will not be ubiquitous this decade. I sure hope they solve it soon but I won't bet the farm on it.
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jvito
1 Comment
Re: The Future
i wouldn't bet the farm on it but i could prolly spare a cow or two seeing how many breakthroughs is happening. they may be at 5% storage capacity of a li battery..i'd think that 20% or maybe even 50% is probable in the next few years.
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jJackWillard
4 Comments
Re: The Future
There is a patented technology presently available which uses activated carbon but produces 15-20 times the storage per gram than the present ultracapacitors on the market. It is cheap to manufacture and utilizes more of the inate capabilities of AC. (Surface area and Conductivity), FYI: A paper was presented at this year's Boston CleanTech by Dr. Carl Nesbitt. This is sleeper!
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jJackWillard
4 Comments
Re: The Future
Is there a typo in the article? It says they reached 236 sq. meters per gram. There are activated carbon electrodes with 1700 or better. Maybe I am missing something.
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protn7
72 Comments
Re: The Future
I was wondering about that too. They say that the high connectivity from the vertically aligned nanotubes increases the storage capacity.
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