TR: This would help address the problem of carbon dioxide as a greenhouse gas, wouldn't it?
GO: Sequestration [of carbon dioxide] is our [government's] official policy and this is what everybody is swearing by. They say that you stick carbon dioxide down into the earth and at the bottom of the sea, and you solve the problem. [But] how long will it stay down there? Carbon dioxide is a very volatile material. Under the best of conditions it eventually will seep up. Our approach is very different: we simply say that if we need to dispose of carbon dioxide, we need to capture it -- why not use it as a chemical raw material? In other words, recycle it.
TR: We've heard a lot lately about replacing gasoline with ethanol from biological sources and developing better batteries for super-efficient hybrid cars. Do these have a place in a methanol economy?
GO: I think we should explore all possibilities. There is no silver bullet. There is no single solution. I sincerely believe, however, that if you look really impartially, but hard-nosed, at the figures, the needs are so enormous that biological sources per se won't solve them. The president mentioned making ethanol from cellulosic materials. In principle it's possible, but it's a very difficult, undeveloped, and, in my mind, unrealistic technology. Batteries, sure, we should try to find better batteries. But realistically today, fuel cells are a lot more convenient than any battery.
TR: What steps need to be taken now to move toward a methanol economy?
GO: I'm a great believer that technological development is done by major companies. ExxonMobil certainly has some means to do it. The only trouble is that so far they are not coming up with any reasonable solution. Basically, I don't think they like [the methanol economy] very much. If you sit on a large supply of oil and gas, on which you make enormous profits, or if you are an Arab country that has great supplies and great wealth, you wouldn't welcome some crazy guy who comes up and says that mankind can have an ultimate solution which would not be dependent, anymore, on what nature put under your soil.
If this methanol economy makes sense, and I think it does, there is not necessarily a monopoly any more for oil companies. Big chemical companies could equally well do this, or even better. But there is also a need for politicians and the public to say that they want to explore reasonable solutions.
TR: How urgent is the problem?
GO: Man began to use coal on a massive scale during the Industrial Revolution, which was, what, 250 years ago. And we are already, to a very significant degree, depleting what nature gave us. Now, I'm not saying we'll run out of it overnight, but we need to think about how we manage our problems now and how we will manage in the future.
You see natural gas getting in short supply, and we import liquefied natural gas. There are many natural gas sources -- Nigeria, the United Arab Emirates, the North Sea, and so on. The energy content of a single LNG tanker is equivalent to a medium-sized hydrogen bomb. Bad guys are trying to blow up refineries now, and a big tanker is a very inviting target. Who can guarantee that some crazy terrorist won't blow up an LNG tanker? I think a realistic solution is, again, to convert natural gas, as efficiently as we can, into a safe liquid product, like methanol.
All people believe that what they are doing has some importance; but this [methanol research] is, in my mind, the most important thing I ever did in my career, and it has serious implications for society.
Home page image courtesy of the University of Southern California.
Comments
03/02/2006
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03/02/2006
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04/24/2006
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04/28/2006
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Combustion engines are not very efficient at converting gasoline to energy.
The electric cars excluding the energy source are highly efficient, I've read over 90%.
Throw in a (I believe) 50% efficient hydrogen fuel cell (It wouldn't surprise me if the methanol fuel cell is around 50%) and it's still 45% efficient.
I think a combustion engines have only got to 30%? (It can depend if it's used as direct power or a series hybrid)
05/02/2006
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05/07/2006
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05/05/2006
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06/02/2006
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ckcress
01/25/2007
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contact me at: DrBrittBorden@gmail.com
BrittBorden
04/16/2009
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03/02/2006
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sudarto
09/29/2006
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I am interested in learning more about the production of methanol from CO2. Please forward to me any material or address of material that will help my education in this field. Thank you and I appreciate any help available.
jh johnh@icminc.com
kittycat
08/16/2007
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BrittBorden
04/16/2009
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03/02/2006
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How about a co-producing metnanol at an ethanol plant and getting more product in liquid form from one plant?
03/02/2006
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03/02/2006
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03/02/2006
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BrittBorden
04/16/2009
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03/02/2006
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03/02/2006
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03/02/2006
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05/16/2006
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By comparison an acre of solar panels near Tucson Arizona could yield a million kwh per year. Electrolyzing water at a rate of 50 kwh per kg hydrogen would yield a 20000 kg/year feedstock stream which when reacted with CO2 could produce 35000 gallons of methanol. The rub ofcourse is the cost of the solar panels.
08/14/2006
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BrittBorden
04/16/2009
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Brian H
07/13/2009
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03/02/2006
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03/02/2006
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03/02/2006
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03/02/2006
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03/02/2006
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futtemi
12/01/2006
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Batteries, BTW, are on a steep energy density growth curve. They will hold 5-10X more within 5 years.
Brian H
07/13/2009
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03/02/2006
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BrittBorden
04/16/2009
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03/02/2006
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http://en.wikipedia.org/wiki/Fischer-Tropsch
03/02/2006
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03/02/2006
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The problem with Fischer Tropsch is the CO2 emission. This CO2 could be recycled, e.g. by nuclear produced electricity or hydrogen and heat and be converted into more synthetic hydrocarbons.
futtemi
12/01/2006
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I'm pro - forward thinking, but concerned this may have equally - if not, more lethal consequences if an accident occurs.
03/02/2006
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BrittBorden
04/16/2009
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Brian H
07/13/2009
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03/02/2006
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About 15-20 years ago a fellow by the name of Dr. Alvin Marks claimed to have theoretically developed a photovoltaic devise with a maximum efficiency of 80%. Believe the roll type photocells on the ISS were of this type. Whatever happened to this? If had the right potential, efficient and economical with volume production.
03/02/2006
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I cannot believe any photovoltaic outside of comic books could have anything like 80% efficiency over the visible spectrum. If you focus on one wavelength, you loose much of the rest. Some day, perhaps. Now, in reality, nuclear works. It could power all these other schemes.
03/03/2006
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Check the legal history ($ouch$) of methanol spills near airfields and raceways and other high performance engine fuel storage areas. Methanol dissolves into water. Creating and storing large volumes of methanol will lead to spills, leaks, and other issues for community fresh water supplies. I sure hope it is possible to cost effectively tweak the CO2 to methanol conversion process so that ethanol is the result.
03/03/2006
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paying $15/mcf a few weeks ago,,
03/03/2006
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futtemi
12/01/2006
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Dr. George Olah knows what he is talking about. Methanol is a very good alternative fuel.
03/03/2006
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03/04/2006
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06/02/2006
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03/17/2006
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Sure it evaporates and breaks down easily. But you couldn't get near a spill without a SCUBA tank setup.
05/09/2006
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Also, electricity is a bugger to move over long distances. Just look at the losses in sending French nuclear energy to the UK through the channel cables. Something liquid with a high energy density would get round that problem and you could sensibly transport solar energy, for example from Arizona to New England.
I don't know if methanol is the best solution for this. Something with less impact on the environment from spills would be nice, but the principal is good.
03/08/2006
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And I can't believe people are still talking nuclear: a fuel that takes years to produce and burn, and remains deadly for thousands of years, not to mention a top terrorist target.
03/14/2006
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http://www.skywindpower.com/ww/index.htm
04/19/2006
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tbagg
04/05/2007
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04/25/2006
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04/28/2006
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The water-based economic model however, focuses in stage one on 2 billion people in South Asia to enable them to generate at least 1 KW/hr of continuous power.
The model is not particularly concerned about the profligate lifestyle of the USA nor propoing up that level of energy consumption.
06/05/2006
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07/25/2006
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In the discussion between electricity/hydrogen/hydrocarbons for road transport two huge fossil users were forgotten, namely aviation and small combustion facilities like heating systems. Aviation in the US currently consumes about 3E18 J/yr and this fuel will probably never be replaced neither by hydrogen nor electricity. With this argument alone, there is a massive market for synthetic liquid hydrocarbons around. Electricity and hydrogen can be generated by a suitable, country dependent mix of renewables and nuclear and the CO2 can be recycled from flue gas. This way one can produce methanol or syngas, and from there almost any other organic chemical.
Does anyone know the process efficiency of:
a) CO2 + H2 + electricity <--> methanol
b) CO2 + H2 + process heat <--> methanol?
Thanks
futtemi
12/01/2006
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Let's produce it managing forest wood (or kind of cellulosic biomass) in countryside and solar electricity in city side. Night nuclear plants overproduction will helps in short/mid term economy transition.
Strictly efficiency requirements and overall energy consumption regulations are required to give the rest.
What are macro-economy implications for oil net buyers? this is citizens health, wealth and happiness?
Do you like forest? Me too.
joancalduch
11/07/2007
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BrittBorden
04/16/2009
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ziko
03/25/2008
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