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Wednesday, October 15, 2008

Water-Repelling Metals

New metals will keep engines and turbines dry and ice-free.

By Prachi Patel-Predd

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Staying dry: A chemically treated plastic surface is rough on the nanoscale, forcing water droplets to form beads that can roll off. GE researchers have now done the same with metal.
Credit: GE Global Research Center

Researchers at GE have come up with a way to treat metals so that they repel water. The extreme water-repelling property, called superhydrophobicity, means that water forms drops on the surface instead of spreading and sticking to it.

The advance builds on previous work that came out of GE's Global Research Center, in Niskayuna, NY. Two years ago, researchers showed that they could make Lexan--a widely employed plastic that's used to create CDs, iPods, aircraft windscreens, and car headlamps--water-repellant. They did this by chemically treating the surface to make it rough. The researchers have now demonstrated the same effect on metal surfaces.

Many other superhydrophobic materials have been demonstrated, but most have used some kind of plastic. Superhydrophobic metals open up many new applications, says Jeffrey Youngblood, a professor of materials engineering at Purdue University. "Metallic structures are more robust and can survive in harsher environments, allowing for their use in applications where plastic is infeasible, [such as in] planes, trains, automobiles, heavy machinery, and engines," Youngblood says.

GE has some ideas about how to use the materials. One possibility is in de-icing aircrafts. Ice buildup on engines due to condensation can be catastrophic. Right now, aircraft use heat to prevent ice, which requires power. De-icing on the ground, meanwhile, is done with de-icing fluids, which contain toxic chemicals; spraying aircraft with de-icing fluids on the ground also takes a lot of time. "It would be very desirable if we could . . . just be able to have a material on which ice didn't stick," says Margaret Blohm, advanced technology leader for the nanotechnology program at GE's Global Research Center.

Another application for the metals could be in gas and steam turbines. The superhydrophobic metals could reduce the buildup of moisture and contaminants on the turbines, increasing their efficiency and requiring fewer shutdowns for maintenance.

GE researchers have not published their work, and they declined to divulge much about their research achievements. But they do say that their inspiration comes from lotus-plant leaves, which have a nanocrystalline wax structure. On the leaf's surface are tiny wax crystals tens of nanometers wide, which hold water drops as almost perfectly spherical beads.

Blohm says that the team is toying with two different approaches to making the metals. One is to texture the metal surface and then put a water-repelling chemical coating on it. The other approach is to leave the metal surface untouched and texture the coating itself. The technique is very general and should work with metals currently used for engines and turbines, such as titanium alloys.

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Comments

  • ship application?
    lawrence.smallman on 10/15/2008 at 1:18 AM
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    Would using this technology on ship hulls not only reduce resistance but also reduce corrosion?
    Rate this comment: 12345
    • Re: ship application?
      phoenix on 10/15/2008 at 11:45 AM
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      An excellent question Lawrence. Can anyone give him some feedback on it? Plus, would this application also help repel barnacles?
      Rate this comment: 12345
  • Biological Paradigms and Biomimetics
    BiomimeticsRegistry.Net on 10/15/2008 at 12:43 PM
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    The 'Lotus effect' noted here is an excellent example of a biological paradigm at work, one that has evolved in certain plants to keep their leaf surfaces clean. New biological paradigms are being revealed on an almost weekly basis and thanks to on-going developments in nanotechnology these too are inspiring new engineering and material science developments leading to valuable and exciting product innovations. More examples of biological paradigms proving especially useful can be found at http://www.biomimeticsregistry.net If nothing else, these biomimetic developments should further underscore the urgent need for conserving biodiversity, something which is being lost at a very alarming rate. 
    Rate this comment: 12345
  • Dirt?
    cyberpageman on 10/15/2008 at 1:24 PM
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    What happens to the water-repellent surface when it gets dirty?
    Rate this comment: 12345
    • Re: Dirt?
      pkassebaum on 10/15/2008 at 10:43 PM
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      like a lotus flower that pristinely rises from the muddy water, materials using the lotus effect will have dirt washed away with the water that glides smoothly off them.
      Rate this comment: 12345
      • Re: Dirt?
        malaeum on 10/16/2008 at 1:14 AM
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        Well that works for water soluble forms of dirt. Oils on the other hand may not be so easily removed if the surface interactions prove to be hydrophilic.
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        • Re: Dirt?
          mcberta2 on 10/16/2008 at 7:26 AM
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          But oil, on the other hand, isn't water so the corrosion protection still stands.
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  • Solar energy application
    mnphysicist on 10/15/2008 at 6:42 PM
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    This might be very useful in solar energy, both in the collector, but also the heat exchanger.
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  • Stability?
    Aziz Abdulagatov on 10/18/2008 at 1:25 AM
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    Possible problem I see here is that hydrophobic film will have low temperature stability and if the film is not covalently bonded to the substrate it just “sits” on it until...
    Rate this comment: 12345
  • Engine surfaces
    jonallen on 10/29/2008 at 8:34 AM
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    This textured hydrophobic surface could help engines to reach their optimum operating temperature much faster, as well as to ward off corrosion. I believe that a deep texture could handle oil without degradation, allowing the oil to drip off once the engine reaches its operating temperature. This is a technology with numerous possible applications.
    Rate this comment: 12345
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