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Kevin Bullis is Technology Review’s energy editor.

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Friday, October 02, 2009

Capturing Carbon Dioxide from the Air

One researcher argues it might be cheaper than offsetting coal emissions with solar power.

One way to counteract the rise in greenhouse gases in the atmosphere is to make use of known chemical reactions to capture carbon dioxide from the atmosphere and store it underground or use it to make something useful like hydrocarbon fuels or plastics. The process is similar to what plants do as they convert carbon dioxide into roots and leaves, but using industrial processes might make it happen faster and on a larger scale.

The question is whether this can be done cheaply enough to be worthwhile. Some have argued that the existing processes are too expensive, and that what's needed is basic research to find chemical reactions that require less energy, among other things. Meanwhile, it's better to try capturing carbon dioxide from smokestacks, where it's much more concentrated, making the capture process cheaper.

David Keith, director of the energy and environmental systems group at the University of Calgary, argues in next week's issue of Science that air capture (as capturing carbon dioxide from the atmosphere is often called) could be cheaper than people think, and that it may make more sense than other methods of offsetting carbon dioxide that are being used today.

He's careful to point out that the economics are by no means certain at this point. Indeed, he argues that what's needed now is funding for some large-scale tests to determine how much various processes really will cost. But his early research, including preliminary work with a startup company, suggests that costs for at least one part of the process--collecting carbon dioxide molecules from the air--will be cheaper than once thought, he says. What's more, such systems could be located anywhere in the world, making it possible to choose a location with low construction costs and easy access to geological structures for storing the carbon dioxide, both of which would make the process cheaper. Carbon dioxide capture from smokestacks, in contrast, must be done near existing power plants, where construction costs and the cost of transporting carbon dioxide to storage sites are higher.

Carbon dioxide capture from smokestacks will probably still have the edge, he says. But air capture may prove cheaper than other methods that are being funded now, such as putting solar panels on roofs in dark regions (Germany, for example), where payback times for the solar panels are very long.

Whether or not it makes sense to fund demonstration projects or to focus on basic research, air capture will likely play an important role in addressing climate change in the coming century. Even with strict emissions cuts in place, the carbon dioxide already in the atmosphere could cause serious problems. Air capture could provide a way to actually reduce greenhouse-gas concentrations, rather than merely stopping their growth.

Comments

  • What technologies are most promising?
    I've heard of cement capture, photobioreactors (Joule Biotechnologies, for example), genetically-modified algae, seeding the ocean with iron and reforestation. What other approaches are being pursued?
    Rate this comment: 12345

    ryanhuber
    10/02/2009
    Posts:3
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  • In my opinion, NH3 is the most promising.
    You have asked what we believe is the most promising energy source. I would like to cast my vote for anhydrous ammonia, or NH3, because I believe that because it's easy to make, easy to transport and there's already a 18 Million Ton NH3 market in the US alone. There's infrastructure to support it already.

    When used as a fuel, NH3 emits only water vapor and NOx. It is often called the "Other hydrogen" because it's so clean.

    NH3 is a fairly easy fuel to make. Currently NH3 is made mainly from natural gas and coal, but it could easily be mode from almost any biomass using anaerobic digestion and a Haber-Bosch reactor. an acre of sweet sorghum could be converted to 1850 gallons of liquid ammonia with a total energy content of 95 million Btu. This would be compared to ethanol from an acre of corn which would produce 560 gallons of ethanol with a total energy content of 44 million Btu, or 1185 gallons of ethanol from an acre of a cellulosic biomass crop with a total energy content of 93 million Btu. It should be noted that the ethanol in this case contains 52% carbon by weight, and the ammonia contains zero carbon.

    Previously I said that the infrastructure for this is already here, and I would like to go back to that. There are more than 800 outlast for NH3 in Iowa alone. Not to put that in perspective; California only has two or three E85 pumps in the whole state, yet California has a huge E85 market.

    My vote is definitely for NH3, how about you?
    Rate this comment: 12345

    zachman1094
    10/05/2009
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    • Re: In my opinion, NH3 is the most promising.
      Wait a second - one of the byproducts of combustion is "NOx"?  As in nitrates of oxygen?  I believe that's a fairly nasty pollutant - I know they go to significant lengths to control it as an emission from automobiles.

      Unless I'm misunderstanding this, I think that's a significant barrier to annhydrous ammonia as a fuel.
      Rate this comment: 12345

      AMcA
      10/12/2009
      Posts:2
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  • Why doesn't anyone know about this?
    This has been my favorite for quite a while now. The byproduct is so entirely innocuous that you can drink it.
    Greenfuel
    Rate this comment: 12345

    chryse
    10/05/2009
    Posts:1
  • Carbon capture
    In my previous comment I was wondering specifically about methods for pulling carbon out of the air, not energy sources. However, the two are intimately related in their impact on atmospheric chemical cycling. I imagine that to wean ourselves off fossil fuels, we'll have to invest in all technologies: genetically-modified organisms to produce various biofuels, wind generation, nuclear, geothermal, conservation, supergrids, intelligent metering, advanced batteries, etc. As far as carbon capture is concerned, I think reforestation is the most promising (and easy to implement) approach. Photobioreactors are the most exciting technological fix I've heard about so far.
    Rate this comment: 12345

    ryanhuber
    10/05/2009
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  • Reforestation
    A forest only is net carbon sequestering for about 50 years. After that, decay of forest debris emits CO2 as fast as the trees grow. Also, preparing a site for planting trees releases significant CO2. Planting trees might help slightly in the short term, but reforestation is not a long term answer. Well intentioned companies that used to sell new trees as carbon offsets have realized that it is ineffective and stopped. And using land for trees competes with food production.
    Rate this comment: 12345

    cmorganmd@gm...
    10/05/2009
    Posts:2
    • Re: Reforestation
      Reforestation does work if wood is harvested once a forest reaches maturity and the carbon can then be used as building material or be carbonised and added to the soil or used for other productive purposes.

      There are loads of ecosystems around the world which need to be rebuilt. The country of Haiti is a good example, at some point their environment is going to have to be restored, soils and vegetation will have to be rebuilt. It will provide long term benefits for the economy of Haiti.
      Rate this comment: 12345

      DJTal
      10/06/2009
      Posts:145
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      • Re: Reforestation
        Your comments about harvesting and using the lumber are interesting. However, wood has a finite life whether in buildings or in the scrap heap after the building has been torn down. I think trapping CO2 in wood only slightly prolongs the inevitable cycle, from dust to dust.
        Rate this comment: 12345

        cmorganmd@gm...
        10/07/2009
        Posts:2
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