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Coming clean: A micrograph shows the surface of a light-activated catalyst that disinfects water even in the dark. Palladium nanoparticles on the surface of a nitrogen-doped titanium oxide help to extend the catalyst's disinfection power up to 24 hours.
Shang, et al. University of Illinois at Urbana-Champaign
New light-activated catalyst keeps on working even after the lights go out.
Getting access to clean drinking water is an ongoing problem for people in developing countries. And even cities that have good water-treatment systems are looking for better ways to deliver safer, cleaner water. Now an international research team has developed a photocatalyst that promises quick, effective water disinfection using sunlight or artificial light. What's more, the photocatalyst keeps working after the light is turned off, disinfecting water even in the dark.
It has long been known that irradiating water with high-intensity ultraviolet light kills bacteria. Some water filters made for campers and hikers, for example, use this technology. Researchers have been working to enhance the method's effectiveness by adding a photocatalyst that gets activated by UV light and generates reactive chemical compounds that break down microbes into carbon dioxide and water.
The new photocatalyst improves on that by using visible, rather than UV, light. Synthesized by Jian-Ku Shang, professor of materials science and engineering at the University of Illinois, Urbana-Champaign, and his colleagues, the photocatalyst works with light in the visible spectrum--wavelengths between 400 and 550 nanometers. It consists of fibers of titanium oxide--a common material used as a white pigment--doped with nitrogen to make it absorb visible light. Alone, the nitrogen-doped titanium oxide kills bacteria, though not efficiently. The researchers added nanoparticles of palladium to the surface of the fibers, greatly increasing the efficiency of the disinfection. He and his colleagues at the Shenyang National Laboratory for Materials Sciences in China published their work online in the Journal of Materials Chemistry.
"It would be very nice to shift activity of the traditional [photocatalyst] materials, which were only activated by ultraviolet radiation, to visible," says Alexander Orlov, assistant professor of materials science and engineering at Stony Brook University in New York. "If you look at the solar spectra, it contains only 5 percent ultraviolet and around 46 of visible." Such photocatalysts would allow solar energy to be used more efficiently as well as used indoors, since fluorescent lighting contains very little ultraviolet light.
Shang and his colleagues tested the photocatalyst by placing it in a solution containing a high concentration of E. coli bacteria and then shining a halogen desk lamp on the solution for varying lengths of time. After an hour, the concentration of bacteria dropped from 10 million cells per liter to just one cell per 10,000 liters.
Promising yes. But has the process been evaluated for biohazards - bits of catalytically reactive nanomaterial in the water supply don't sound like fun. A little light could get through to water in the stomach and do something reactive. Or would you just coat a solid and keep the particles from moving about?
I agree about the bio-hazard angle. For example, what would this photo-catalyst system do to the bacteria in the digestive system? It seems that the catalyst if successful should be carefully confined and controlled within water treatment facilities!
Catalyst contained within filter?
I had the impression that the catalyst was contained within the filter rather than mixed into the water. This would, hopefully, limit concentrations of nano-particles in the water, if I am correct. Otherwise the process also seems very wasteful of catalytic material in addition to unknown biohazards.
Side question. How abundant is palladium? Is there enough for widespread use or is this more a proof-of-principle experiment, perhaps also looking for similar catalysts utilizing more abundant elements.
Caveats aside, sounds like a very interesting and possibly fruitful experiment. The life-saving potential in relief efforts after natural disasters is obvious, as it is in areas lacking pure water supplies.
Also, any antiviral activity?
Re: Catalyst contained within filter?
Estimated Crustal Abundance:
Platinum: 0.005 mg/kg
Gold: 0.004 mg/kg
Silver: 0.075 mg/kg
Palladium: 0.015 mg/kg
Translation: rare, and not cheap. Commonly found in catalytic converters used in cars.
Like all "nano" products toxicity needs to be throughly tested before this idea can ever be used in the water supply. As even if bound in some sort of filter matrix it is goig to get out.
The reproducibility of the photocatalyst?
Due to the narrow band-gap of the Titanium oxynitride or Titanium nitride, it is sure that the nitrogen-doped TiO2 could be used as visible-light photocatalyst.However, nitrogen-doped TiO2 is not stable under the light illuminations, which means it could be gradually transfered to TiO2 and lose their visible-light photocatalytic abilities. So i quite wonder the reproducibility and feasibility of the photocatalyst.
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11 Comments
Very impressive
This is a very impressive development. Is this temporal stability or "memory effect" induced by the palladium (sliver) nano-particles a well known phenomena? It appears to be a rapid "charging" system for converting photons into electron hole pairs. Any clue on the efficiency of the conversion?
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