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TR35

2009 Young Innovator

Kurt Zenz House, 31

C12 Energy

Capturing carbon dioxide through cement production

About 5 percent of global carbon dioxide emissions come from manufacturing cement. Kurt Zenz House, a research fellow at MIT and cofounder of a startup called C12 Energy, hopes to turn the problem into a solution. He thinks that the carbon dioxide from industrial smokestacks can be captured for use in cement production--keeping it out of the atmosphere for good.

The key to his approach is that alkaline solutions react with carbon dioxide and trap it in various compounds. For example, lye reacts with carbon dioxide to form baking soda. Combining the baking soda with seawater creates a type of cement, the glue that holds concrete together.

House says that regulations designed to limit greenhouse-gas emissions, such as a carbon tax, could eventually make this process profitable as well as environmentally sound. Meanwhile, he's researching other ways to store carbon dioxide, including sequestration under the ocean and in geologic reservoirs on land. And at C12, he's developing technology to reduce the cost of storing carbon dioxide. --Kevin Bullis

Turning carbon into cement: Kurt House has a simple recipe: Start with seawater. Extract the sodium chloride from the other minerals to make salt water. Electrolyze that, splitting the water and salt to form sodium hydroxide (lye) and hydrochloric acid. Neutralize the acid in a reaction with silicate rocks, producing sand and magnesium chloride, which can be used together or separately to melt ice on roads. Combine the highly alkaline sodium hydroxide solution with carbon dioxide streaming from a smokestack, trapping the carbon dioxide in the form of baking soda (sodium bicarbonate). Add the baking soda to seawater, which contains magnesium and calcium. The soda triggers a series of reactions, precipitating a magnesium and calcium carbonate that can be used as cement.
Credit: Arthur Mount

 
 
TR35 Back to all TR35 2009 Winners   TR35 2009 Energy Winners     
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Kurt Zenz House
Capturing carbon dioxide through cement production
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Nanoporous carbon could help power hybrid cars

Comments

  • Turning CO2 into Cement
    Interesting concept but question the possible economics.  Many of the precursors require input that are either not free and or have thier own carbon footprint such as the electrolytic cell.  Producing NaOH by electrolysis is never done as a primary source.  The NaOH is usually the byproduct of a higher value product (such as Chlorine).  Upto a year or two ago, bicarbonate production lagged because its precursor (soda ash from trona or brines) was more valuable.

    Finally, the majority of the cement produced is verly low on the magnesium content.  Magnesium content in cement powders above 4-5% tends to lead to expansive cements.  If the Mg contents are high, then the resulting cements would be limited to low value uses such as soil cements and the like.  These low value uses would further drive up the economic hurdles.
    Rate this comment: 12345

    bglackin
    08/19/2009
    Posts:1
    Avg Rating:
    5/5
    • Re: Turning CO2 into Cement
      Magnesium can become a part of the total cement as magnesium oxychloride if chemistry is right. I do agree that the concept has not proven on an industrial scale and is far from it.
      Rate this comment: 12345

      admin
      10/12/2009
      Posts:1
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