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Carbon dioxide in concrete: This micrograph shows the crystal structure of concrete cured in the presence of carbon dioxide. A Canadian company says that its curing process can store 60 tons of carbon dioxide inside 1,000 tons of precast concrete products, such as concrete blocks, while saving energy.
Carbon Sense Solutions
A new process stores carbon dioxide in precast concrete.
A Canadian company says that it has developed a way for makers of precast concrete products to take all the carbon-dioxide emissions from their factories, as well as neighboring industrial facilities, and store them in the products that they produce by exposing those products to carbon-dioxide-rich flue gases during the curing process. Industry experts say that the technology is unproven but holds great potential if it works.
Concrete accounts for more than 5 percent of human-caused carbon-dioxide emissions annually, mostly because cement, the active ingredient in concrete, is made by baking limestone and clay powders under intense heat that is generally produced by the burning of fossil fuels. Making finished concrete products--by mixing cement with water, sand, and gravel--creates additional emissions because heat and steam are often used to accelerate the curing process.
But Robert Niven, founder of Halifax-based Carbon Sense Solutions, says that his company's process would actually allow precast concrete to store carbon dioxide. The company takes advantage of a natural process; carbon dioxide is already reabsorbed in concrete products over hundreds of years from natural chemical reactions. Freshly mixed concrete is exposed to a stream of carbon-dioxide-rich flue gas, rapidly speeding up the reactions between the gas and the calcium-containing minerals in cement (which represents about 10 to 15 percent of the concrete's volume). The technology also virtually eliminates the need for heat or steam, saving energy and emissions.
Work is expected to begin on a pilot plant in the province of Nova Scotia this summer, with preliminary results expected by the end of the year. If it works and is widely adopted, it has the potential to sequester or avoid 20 percent of all cement-industry carbon-dioxide emissions, says Niven. "If the technology is commercialized as planned, it will revolutionize concrete manufacturing and mitigate hundreds of megatons of carbon dioxide each year, while providing manufacturers with a cheaper, greener, and superior product." He adds that 60 tons of carbon dioxide could be stored as solid limestone--or calcium carbonate--within every 1,000 tons of concrete produced. Further, he claims that the end product is more durable, more resistant to shrinking and cracking, and less permeable to water.
"It almost sounds too good to be true," says civil engineer Rick Bohan, director of construction and manufacturing technologies at the Portland Cement Association, in Skokie, Illinois. He points out that the idea of concrete carbonation has been around for decades but has never been economical as a way to strengthen or improve the finished product. In the late 1990s, researchers showed how carbon dioxide could be turned into a supercritical fluid and injected into concrete to make it stronger, but the required high pressures made the process too energy intensive. Carbon Sense Solutions claims to achieve the same goal but under atmospheric pressure and without the need for special curing chambers. "I'd be really skeptical," adds Bohan. "But if someone has a revolutionary process, we'd love to see it."
Does this apply to AAC blocks?
Aerated autoclaved concrete is attractive as an inert insulating block, but it obviously requires autoclaving to cure the foamed concrete. The autoclaving not only adds to the cost, but also to the carbon gas emissions from the burning of coal to produce the steam.
AAC blocks and panels can replace standard concrete blocks for many application, and for green construction are getting a lot of attention.
But their cost in dollars and CO2 emissions are short term obstacles.
If concrete is 5% of human CO2 emissions, and this new concrete reduces emissions by 20%, then that's a 1% reduction of total emissions.
Nice - every little bit helps - but not spectacular.
By the time this tech is widely implemented, concrete use will highly likely be much larger than 120% of today's levels, making total CO2 emissions from concrete bigger than today.
I believe it is the manufacturing of cement NOT concrete that is 5% of man-made C02 - can someone confirm?
The Carbonation of Dense Concretes
1. There are no technical or sequestration advantages in using considerable energy to make Portland cement in which silicates and to a lesser extent aluminates predominate only to carbonate them as many researchers are attempting to do.
2. The carbonation of Portlandite which is a minor but significant component formed on the hydration of Portland cement increases strength but lowers the pH resulting in the break down of the passive oxide layer on steel and thus corrosion.
3. How carbonation occurs depends mainly on the maturity of the concrete, the partial pressure of CO2, humidity and permeability.
4. The construction of special carbonation rooms near point sources of CO2 and the logistics involved in moving either fresh concrete or finished product to such rooms or other facilities is and will become increasingly more prohibitive.
5. Because the carbonation of silicate and aluminate phases occurs much more readily in uncured concretes it is not only cheaper but technically much better to optimise natural carbonation. Better microstructure as well as chemical stability is the main outcome.
6. It is also more economical to naturally carbonate concretes provided rate issues and in the case of pre-mix concrete, pH issues if steel reinforcing is to be used, can be overcome.
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jaywetmore
1 Comment
Carbonation of Concrete
For engineers evaluating the condition of concrete to determine remaining life, the extent of carbonation is an important indicator. The closer the carbonation is to the reinforcing steel the shorter the remaining life. Concrete's high alkalinity inhibits the oxidation of the reinforcing steel. Carbonation neutralizes the concrete, resulting in less protection for the metal reinforcement.
Carbonation is contra-indicated for reinforced and prestressed concrete. It is ok in unreinforced concrete like you might find in a sidewalk.
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Siphon
152 Comments
Re: Carbonation of Concrete
Reinforced concrete can be done with other materials, such as composites. They don't oxidize much at all. This is an emerging industry because it's possible to make higher quality reinforced concrete.
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ralph@bfmarch.com
1 Comment
Re: Carbonation of Concrete
"Concrete's high alkalinity inhibits the oxidation of the reinforcing steel." Sounds like more, not less protection for the steel against rusting. What am I missing?
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