Thursday, March 13, 2008

Toward Cheaper, Robust Solar Cells

Researchers are working on solar cells that use a novel organic dye.

By Prachi Patel-Predd

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Making solar cheaper: Dye-sensitized solar cells, which are cheaper than silicon cells, consist of dye-coated titanium dioxide nanoparticles immersed in an electrolyte solution, which is sandwiched between glass plates. A new combination of electrolyte and dye promises to make these solar cells even cheaper and more robust. Key to the innovation is an organic dye molecule.
Credit: Alex Agrios, Northwestern University

Cheap and easy-to-make dye-sensitized solar cells are still in the early stages of commercial production. Meanwhile, their inventor, Michael Gratzel, is working on more advanced versions of them. In a paper published in the online edition of Angewandte Chemie, Gratzel, a chemistry professor at the École Polytechnique Fédérale de Lausanne in Switzerland, presents a version of dye-sensitized cells that could be more robust and even cheaper to make than current versions.

Dye-sensitized solar cells consist of titanium oxide nanocrystals that are coated with light-absorbing dye molecules and immersed in an electrolyte solution, which is sandwiched between two glass plates or embedded in plastic. Light striking the dye frees electrons and creates "holes"--the areas of positive charge that result when electrons are lost. The semiconducting titanium dioxide particles collect the electrons and transfer them to an external circuit, producing an electric current.

These solar cells are cheaper to make than conventional silicon photovoltaic panels. In principle, they could be used to make power-generating windows and building facades, and they could even be incorporated into clothing. (See "Window Power" and "Solar Cells for Cheap.") A Lowell, MA-based company called Konarka is manufacturing dye-sensitized solar cells in a limited quantity. But the technology still has room for improvement.

In existing versions of the solar cells, the electrolyte solution uses organic solvents. When the solar cells reach high temperatures, the solvent can evaporate and start to leak out. Researchers are now looking at a type of material that may make a better electrolyte: ionic liquids, which are currently used as industrial solvents. These liquids do not evaporate at solar-cell operating temperatures. "Ionic liquids are less volatile and more robust," says Bruce Parkinson, a chemistry professor at Colorado State University.

New dyes are also being investigated. In commercial cells, the dyes are made of the precious metal ruthenium. But researchers have recently started to consider organic molecules as an alternative. "Organic dyes will become important because they can be cheaply made," Gratzel says. In the long run, they might also be more abundant than ruthenium.

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Toward Cheaper, Robust Solar Cells

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