Technology Review - Published By MIT
Advertisement
« Back 1 [2]

Wednesday, August 15, 2007

Silicon Nanocrystals for Superefficient Solar Cells

Continued from page 1

By Kevin Bullis

smaller text tool iconmedium text tool iconlarger text tool icon

Before the NREL work, researchers had believed that silicon crystals small enough to produce the multielectron effect would be impractical as a photovoltaic material. At the nanoscale, the optical properties of silicon change so that it converts less light from the red end of the spectrum into electrons. As a result, any gains from more efficiently converting blue and ultraviolet light would be offset. Nozik and his colleagues found that the nanocrystals did not have to be as small as was previously thought, skirting this problem.

To be sure, the NREL work is only a first step. Making solar cells that take advantage of multielectron generation is a challenge. That's because the extra electrons are very short-lived, making it difficult to extract them from the nanocrystals to generate an electrical current. Indeed, this has proved so difficult that evidence of the effect has come from indirect methods such as spectroscopy rather than from current generated by a solar cell. The use of the indirect measures has led some prominent experts to question whether the extra electrons are actually being produced, although Nozik says that the effect has been confirmed using multiple techniques. Nozik and his colleagues are now working to make solar cells out of silicon nanocrystals--they're exploring a number of novel designs--and he says they've recently made direct measurements indicating that their cells are releasing multiple electrons per photon absorbed. (Their results have yet to be published.)

Honsberg is cautiously optimistic, calling the finding of the multiple-electron effect in silicon nanocrystals a breakthrough, but only "one breakthrough out of maybe three or four" needed to produce cheap, superefficient solar cells.

« Back 1 [2]

Comments

  • Synergy
    Siphon on 08/21/2007 at 5:17 AM
    Posts:
    112
    Avg Rating:
    3/5
    Wouldn't this be great to combine with other novel silicon technologies, such as Sliver Cells? Or silicon (amorphous) thinfilm maybe?
    Rate this comment: 12345
    • Re: Synergy
      cripdyke on 08/26/2007 at 3:53 AM
      Posts:
      15
      Avg Rating:
      4/5
      I think that, frankly, you failed to understand the article. This tech uses silicon NANOcrystals. Thin films are only valuable because they use less of the  expensive pure silicon crystals grown to large sizes and thicknesses under exacting conditions.

      Nanocrystals are even smaller than thin film, which amounts to slicing the expensive crystals very thin so as to use less of an expensive ingredient and thus keep cost of manufacture lower than otherwise.

      Nanocrystals are in fact so much smaller as to make comparisons a joke, really. Large, pure crystals are not the raw material for nanocrystals. And the nanocrystals cannot be amorphous... because they are crystals.

      Now on the upside, this tech not only gains from the advantages of efficiency inherent in producing different numbers of electrons based on the amount of energy in the striking photon, but since it doesn't start out as a pure crystal -thick disk or thin film- a manufacturer does not incur the expense of paying for the expensive pure-silicon-crystal-growth processes.

      So, the "synergy" with these other techs is effectively already in this one: high efficiency from nano, low costs from avoiding using large amounts of large, pure crystals. And yet it is not synergy at all, nor is it something that we must research to apply. Nanocrystals are not merely thin, they are ridiculously small. "Nano" by definition generally refers to things that are no more than a tenth of a millionth of a meter (100 nanometers or 100nm) in at least 2 spacial dimensions. (Although some "nano" work is in the field of nanofilms that meet this requirement in only 1 dimension, thickness, and are designed to be spread over surfaces for much larger distances than 100nm, often even macroscopic distances.) For these crystals they meet the 100nm criterion in all 3 spacial dimensions. As well, it is impossible for a nanocrystal to be amorphous, in the sense of non-crystalline. If it's a nanocrystal, it's a crystal...just a small one.

      Hope that helps.
      Rate this comment: 12345
      • Re: Re: Synergy
        Siphon on 08/27/2007 at 3:59 PM
        Posts:
        112
        Avg Rating:
        3/5
        Yes it does, thank you. Amorphous? What was I thinking, duh. Unless of course the nanocrystals were irradiated for long periods of time (but why would one do that?)

        The extreme size of the crystals actually sounds very problematic for mass production. How do you deposit these things onto anything adequately and homogeneously? And if that could be done, how do the crystals degrade over time in real world conditions?
        Rate this comment: 12345
        • Re: Re: Synergy
          atsilver on 09/20/2007 at 4:55 PM
          Posts:
          1
          I aggree with Siphon on this last point (his/her second paragraph) and hope to see a reply soon (from concept to lab to technology and from here to commercially available products there is also a long way, sometimes unable to be completed). And this is not a minor affair, nor a problem of correct understanding of the article, but a practical point of view.
          Rate this comment: 12345
Advertisement

Current Issue

Technology Review January/February 2009
Lifeline for Renewable Power
Without a radically expanded and smarter electrical grid, wind and solar will remain niche power sources.
•  Subscribe
Save 41%
•  Table of Contents
•  MIT News

Magazine Services

Career Resources

MIT Technology Insider

Stories and breaking news from inside MIT about the latest research, innovations, and startups--in a convenient monthly e-newsletter. Subscribe today
Advertisement

Follow us on Twitter

Twitter

Get Technology Review updates via the web, cellphone, or Instant Messager – Follow techreview on Twitter!

Advertisement

More Technology News from Forbes

Advertisement
Advertisement
TECHNOLOGY RESOURCES
Advertisement
MIT Massachusetts Institute of Technology