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Thursday, February 22, 2007

Capturing Carbon with Enzymes

Continued from page 1

By Tyler Hamilton

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Don Langley, vice president and chief technology officer for Babcock and Wilcox, says the approach holds more promise for large-scale carbon capture than do some alternatives, such as carbon-dioxide-absorbing algae farms that require huge tracks of land. "We're in serious discussions at the moment on how to move forward with a more formal relationship, which would potentially include licensing the technology and joint development," Langley says, adding that the bioreactor must be scaled up substantially and operate more efficiently to be economical. "We're kind of placing bets, if you will," he says. "Obviously, we see some things in the CO2 Solution approach that I really wouldn't want to disclose that make us pretty interested."

Aluminum giant Alcoa tested CO2 Solution's lab prototype in 2004 by attaching it to an air outlet from a smelter's emissions-scrubbing system. Michel Lepage, Alcoa's director of laboratories and environment, says the technology worked well. "The system removed 80 percent of the CO2, which is quite large," says Lepage, emphasizing that it was a small-scale test. "But it told us it has a high potential."

CO2 Solution also sees its technology serving some industrial niches. Last week the company was granted a European patent for the process of capturing carbon-dioxide emissions from cement factories and converting it into bicarbonate and eventually limestone--a key ingredient in manufacturing the cement itself. The company already holds a U.S. patent on the process. The bicarbonate is also useful for producing carbonate compounds for neutralizing industrial waste and some effluents.

For its part, Babcock and Wilcox is strictly interested in the carbon-dioxide removal, compression, and geologic sequestration; any end-stream products that may result would simply be a bonus. "Quite frankly, it just boils down to what's the dollars-per-avoided-ton cost of CO2," says Langley. "That's our focal point."

Langley emphasizes that CO2 Solution's technology is still very much at an embryonic stage of development and that there are major economic and technical hurdles to overcome. "There's not any technology today that's really down to where we need to be," he says.

The company's techniques for reproducing the enzyme have already led to a significant drop in enzyme production costs. Perhaps the biggest challenge will be to produce enough of the enzymes to process the enormous quantity of carbon dioxide that would be emitted from a coal- or gas-fired power plant. CO2 Solution is determined to do it, particularly given the heightened profile of climate change and the likelihood that carbon regulation is around the corner.

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Comments

  • Half a solution
    hsfrey on 02/22/2007 at 1:59 AM
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    Where do you get all the Calcium or other cation to combine with the bicarbonate? Make it from limestone? <g> You're going to need vast quantities to make a dent.
    So, what cation is very common, easily isolated without a lot of energy, and which has an insoluble carbonate?
    This sounds like half a solution to the problem. But not even that - you don't need the bugs - just dissolving CO2 in water gives bicarbonate.
    Rate this comment: 12345
    • Re: Half a solution
      kearns on 02/22/2007 at 11:03 AM
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      25
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      4/5
      Yes, and sea creatures like coral convert dissolved C02 in the oceans into coral reefs. If you could speed up the process temporarily the oceans could conceivably clear the air of the excess CO2.  Turning it off would be the problem, however.  You could precipitate an ice age if too much CO2 was removed.
      Rate this comment: 12345
      • Re: Half a solution
        pfdietz on 02/23/2007 at 9:34 PM
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        2
        It's my understanding that precipitation of calcium carbonate would actually cause a net release of CO2 from the ocean into the atmosphere.  This is because the inorganic carbon in seawater is mostly in bicarbonate ions, so the reaction is Ca(+2) + 2 HCO3(-) --> CaCO3 + CO2 + H2O.

        On a time scale of centuries, CO2 will be absorbed into the ocean by a process involving the dissolution of calcium carbonate, not its deposition.  On a longer time scale, additional positive ions are added by weathering, and this ultimately leads to carbonate deposition.
        Rate this comment: 12345
  • The great carbon shortage of 2050
    GaryB on 02/22/2007 at 3:25 AM
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    I always thought that when humanity learns to make building materials from carbon like plants do, the demand will eventually outstrip production and we'll go into a carbon shortage crisis where they'll begin mining coal and that sequestered CO2 for manufacturing use.
    Rate this comment: 12345
    • Re: The great carbon shortage of 2050
      branta on 02/22/2007 at 8:50 AM
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      1
      We already have that amazing building material.  It is called timber. We just need to find a better way of producing and harvesting than the one we use now. 
      Rate this comment: 12345
      • Re: The great carbon shortage of 2050
        fat4ol on 02/28/2007 at 10:16 AM
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        1
        My jolly how the world leaders do not see that is beyond me. All this bull dust about emissions! One decent volcanic eruption will put all of humanity efforts of decades to a shame, do they not realize it? What fools! Yet deforestation continues I believe at a football field avery second! HOW LONG!!!??? This is the real problem and how easily fixed! But that will not put $$$$$$$$$$$$$$$$$ in politicians pockets! So do not expect correction soon! Any carbon trading is a pump for $ out of your pocket! Target of any power hungry poli.
        Rate this comment: 12345
        • Re: The great carbon shortage of 2050
          pfdietz on 03/05/2007 at 11:30 AM
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          2
          <i>One decent volcanic eruption will put all of humanity efforts of decades to a shame, do they not realize it?</i>

          They don't realize it, because it isn't true.  CO2 emissions from fossil fuel combustion are much larger than emissions from volcanic sources, and CO2 levels are rising higher than they've been in at least tens of thousands of years (your putative 'decent' volcanic eruptions notwithstanding).
          Rate this comment: 12345
      • Re: The great carbon shortage of 2050
        guestnonamebob on 03/06/2007 at 6:54 PM
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        2
        what about buildings out of carbon nanotubes
        Rate this comment: 12345
        • Re: The great carbon shortage of 2050
          ashalleck on 04/06/2007 at 12:47 PM
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          3
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          5/5
          I wrote about this in an editorial on Nanotech-news that no one seems to have noticed.

          CNT's are amazingly useful creations... CO2 from exhaust gas can be used as feedstock in conversion machinery at plants at small energy   cost and locally derived CNT's in quantity can be stored, used in building construction, roads, etc.
          The process is called recarbonization and produces
          a viable solution to the excess CO2 problem.


          Alan Shalleck
          Nanoclarity LLC
          www.nanoclarity.om
          Rate this comment: 12345
  • Tracks?
    corporatedave on 02/22/2007 at 5:54 PM
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    11
    Tracks: path: a line or route along which something travels or moves

    http://www.google.com/search?q=define%3Atrack&btnG=Search

    Tracts:An area of land bounded by features as described for blocks, or by municipal or county boundaries
    http://www.google.com/search?num=100&hl=en&q=define%3Atracts&btnG=Search

    If you don't believe google, you HAVE to believe Monty Python.

    FATHER:  Don't like her?!  What's wrong with her?  She's beautiful,
          she's rich, she's got huge... tracts of land.

    http://www.sacred-texts.com/neu/mphg/mphg.htm
    Rate this comment: 12345
  • No need for capturing carbon!
    greeninventions.net on 03/07/2007 at 10:54 AM
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    6
    There is no need for capturing carbon. With a for the world little investment (compared to for instance investments in defence or agriculture subsidies) both world energy needs and climate problems can easily be solved. Read for instance http://www.greeninventions.net/wiki/Portal:Solar.
    Rate this comment: 12345
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